Comparison of the Hydrocarbon Distribution in Thermolysis Products of Asphaltenes, Resins, and Acids Isolated from Weakly Transformed Crude Oil from the Anastasievsko-Troitskoe Oil Field (Horizon IV)

IF 1.3 4区 工程技术 Q3 CHEMISTRY, ORGANIC Petroleum Chemistry Pub Date : 2023-12-07 DOI:10.1134/S0965544123060130
G. N. Gordadze, A. V. Vasileva, D. S. Vylekzhanina, G. A. Gadzhiev, O. A. Stokolos
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Abstract

Regular trends in the distribution of hydrocarbon biomarkers (n-alkanes, isoprenanes, steranes, and terpanes) and hydrocarbons of the adamantane series in low-maturity crude oil from the Anastasievsko-Troitskoe oil field (horizon IV) and in products formed by thermolysis of asphaltenes, resins, and acids from this oil were studied by gas chromatography–mass spectrometry. Thermolysis of high-molecular-mass oil precursors yields the same hydrocarbons (HCs) as those present in the initial oil, and also protoadamantanes (precursors of adamantanes). HCs of the adamantane series are not formed, and their presence in this crude oil is due to their supply from other oil source strata. The experiments show that the n-alkanes present in the initial oil in small amounts are released under more severe conditions.

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Anastasievsko-Troitskoe油田弱转化原油沥青质、树脂和酸热裂解产物中烃类分布的比较
采用气相色谱-质谱联用技术研究了Anastasievsko-Troitskoe油田(地平线IV)低成熟原油中烃类生物标志物(正构烷烃、异戊二烷、甾烷和萜烷)和adamantane系列烃类的分布规律,以及该油田沥青质、树脂和酸的热裂解产物。高分子质量油前体的热裂解产生与初始油中相同的碳氢化合物(hc),以及原金刚烷(金刚烷的前体)。金刚烷系列烃没有形成,它们在该原油中的存在是由于它们来自其他油源地层的供应。实验表明,初始油中少量的正构烷烃在较苛刻的条件下被释放。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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