Clinker-efficient cements and their application - today and tomorrow

ce/papers Pub Date : 2023-12-06 DOI:10.1002/cepa.2824
Christoph Müller
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Abstract

The concrete standard DIN 1045-2 currently provides fixed limit formulations for the respective exposure class. The tests of cements in concrete with regard to durability (carbonation, chloride penetration, frost and freeze-thaw salt resistance) are now carried out within approvals procedures in a limit composition for the exposure class under consideration. Test results of clinker-efficient cements are shown against the assessment background of the German Institute for Building Technology (DIBt) e. g. for carbonation: This test is currently to be carried out with a water-cement ratio of w/c = 0.50. While, for example, a CEM III/A or a CEM II/C-M (S-LL) fit well into the assessment background in this test with the required limit composition, the depth of carbonation of a cement is 20 percent clinker, 30 percent blast furnace slag and 50 percent unburned limestone clearly outside. If the water-cement ratio is reduced to w/c = 0.40, the result is already in the upper range of the evaluation background. A further reduction to w/c = 0.35 leads to a result in the range of the reference cements. A further significant reduction in the clinker content in cements with a high proportion of unburnt limestone would therefore be possible if the concretes are composed accordingly.

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高效熟料水泥及其应用——今天和明天
混凝土标准DIN 1045-2目前为各自的暴露等级提供了固定的限值公式。水泥在混凝土中的耐久性测试(碳化、氯化物渗透、抗冻和抗冻融盐性)现在在审批程序内按照所考虑的暴露等级的极限成分进行。高效熟料水泥的测试结果是根据德国建筑技术研究所(DIBt)的评估背景显示的,例如碳化:该测试目前将在水灰比w/c = 0.50的情况下进行。例如,CEM III/ a或CEM II/C-M (S-LL)符合本测试的评估背景,并具有所需的极限成分,但水泥的碳化深度为20%熟料,30%高炉渣和50%未燃烧的石灰石。如果水灰比减小到w/c = 0.40,则结果已经处于评价背景的上界范围。进一步降低到w/c = 0.35,可以得到参考水泥的范围。因此,如果在混凝土中加入高比例的未燃烧石灰石,就有可能进一步显著减少水泥中熟料的含量。
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