Micro-morphologies of SBS modifier at mortar transition zone in asphalt mixture with thin sections and fluorescence analysis

Abstract

The microstructure control of modified asphalt, especially the micro-dispersion of the SBS modifier in the mortar transition zone, is a critical technology for the performance design of modified asphalt. To characterize the micro-dispersive morphology of SBS modifiers, thin-section preparation techniques that can be used to analyze the original microstructure of the asphalt mixture were proposed and introduced in this study. Flexible resin is filled into the mixture at vacuum conditions to ensure accepted sample conditions for preparing thin sections of asphalt mixture. The morphology parameters, including SBS area ratio, box dimension, SBS average particle area and its coefficient of variation, area-weighted average axis ratio, and coefficient of variation, were plotted from fluorescence images to characterize the micro-morphological distribution of the SBS modifier in detail. Results have shown that the area ratio increased with the increase in SBS content, while the box dimension was reduced and the distribution uniformity of the particles decreased. The superfluous SBS modifier in the binder at a too high adding ratio will decrease the value of the box dimension. Lower modification temperature worsened the SBS modifier in the mixture, resulting in a wide range of particle size, higher axis ratio, and higher area ratio. The micro-morphologies of SBS in the asphalt mixture phase varied a lot from the asphalt binder phase. The additional materials of mineral filler and fine aggregate, together with the other heating processes, will significantly influence the swelling state and particle size of the SBS modifier.