Semyon V. Bachinin , Anastasia Lubimova , Svyatoslav A. Povarov , Dmitrii Zubok , Elizaveta Okoneshnikova , Alena N. Kulakova , Sergey S. Rzhevskiy , Valentin A. Milichko
{"title":"Memristive behavior of UiO-66 metal-organic framework single crystal","authors":"Semyon V. Bachinin , Anastasia Lubimova , Svyatoslav A. Povarov , Dmitrii Zubok , Elizaveta Okoneshnikova , Alena N. Kulakova , Sergey S. Rzhevskiy , Valentin A. Milichko","doi":"10.1016/j.photonics.2023.101206","DOIUrl":null,"url":null,"abstract":"<div><p><span>Metal–organic frameworks (MOFs) have recently emerged as a new class of scalable and low energy consumptive materials for microelectronic applications. Here, we experimentally extend the list of MOFs with memristive behavior for electronic data storage. Using 15 µm single crystals of UiO-66 located in 10 µm gap between Au contacts, we demonstrate an electronic set/reset process upon 15 kV cm</span><sup>−1</sup><span> of an electric field strength under normal conditions. Such low-energy data recording together with an endurance of more than 7 cycles for set/reset opens up prospects for the design of MOF-based electronic and opto-electronic devices.</span></p></div>","PeriodicalId":49699,"journal":{"name":"Photonics and Nanostructures-Fundamentals and Applications","volume":"58 ","pages":"Article 101206"},"PeriodicalIF":2.5000,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Photonics and Nanostructures-Fundamentals and Applications","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1569441023001001","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Metal–organic frameworks (MOFs) have recently emerged as a new class of scalable and low energy consumptive materials for microelectronic applications. Here, we experimentally extend the list of MOFs with memristive behavior for electronic data storage. Using 15 µm single crystals of UiO-66 located in 10 µm gap between Au contacts, we demonstrate an electronic set/reset process upon 15 kV cm−1 of an electric field strength under normal conditions. Such low-energy data recording together with an endurance of more than 7 cycles for set/reset opens up prospects for the design of MOF-based electronic and opto-electronic devices.
期刊介绍:
This journal establishes a dedicated channel for physicists, material scientists, chemists, engineers and computer scientists who are interested in photonics and nanostructures, and especially in research related to photonic crystals, photonic band gaps and metamaterials. The Journal sheds light on the latest developments in this growing field of science that will see the emergence of faster telecommunications and ultimately computers that use light instead of electrons to connect components.