Synthesis and Reactivity of Organometallic Platinum Compounds containing one platinum–carbon bond

V. V. Sharutin, A. R. Zykova
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Abstract

Abstract—

Since the discovery of a platinum compound containing the organic ethylene ligand by William Zeise in 1827, organic platinum compounds have attracted the attention of scientists all over the world. With the discovery of new properties of platinum compounds, the areas of their application have expanded: from catalysts of chemical reactions to use in medicine in the treatment of malignant tumors. This review analyzes the methods of synthesis, structural features, and the possibility of their practical use, published from 2020 to 2023. Due to the large amount of literature data on this topic, this review attempts to piece together and systematize the methods of synthesis and properties of organic platinum compounds containing one platinum–carbon bond in their composition. The main tendencies and directions of research into organic platinum compounds are revealed. The most efficient methods of synthesis, the chemical properties, and some reaction mechanisms are presented. Information on biological activity and catalytic and photoluminescent properties is presented.

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含单铂碳键的有机金属铂化合物的合成及其反应性
自1827年威廉·蔡泽发现含有机乙烯配体的铂类化合物以来,有机铂类化合物引起了世界各国科学家的关注。随着铂化合物新性质的发现,其应用领域已经扩大:从化学反应的催化剂到用于医学治疗恶性肿瘤。本文分析了2020年至2023年发表的合成方法、结构特征及其实际应用的可能性。由于这方面的文献资料较多,本综述试图对含一个铂碳键的有机铂化合物的合成方法和性质进行梳理。指出了有机铂类化合物研究的主要趋势和方向。介绍了最有效的合成方法、化学性质和一些反应机理。介绍了其生物活性、催化和光致发光特性。
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