Spectral classification analysis of recycling plastics of small household appliances based on infrared spectroscopy

IF 2.7 3区 化学 Q2 CHEMISTRY, ANALYTICAL Vibrational Spectroscopy Pub Date : 2023-12-06 DOI:10.1016/j.vibspec.2023.103636
Qunbiao Wu , Jiachao Luo , Haifeng Fang , Defang He , Tao Liang
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Abstract

The recycling of plastics from small household appliances is of great significance in improving the environment and addressing resource shortages, and has gradually become a focus of attention in various countries. Firstly, spectra were collected from samples with different colors, oxidation levels, and flame retardants. It was found that samples with different colors and oxidation levels exhibited different reflectivity, while samples with flame retardants showed smaller absorption peaks. Subsequently, the spectrum was preprocessed and analyzed, and the results showed that the samples collected under different conditions had little effect on plastic classification. Finally, plastic spectral classification was carried out using algorithms such as support vector machine (SVM), backpropagation neural network (BP), k-nearest neighbor (k-NN), partial least squares discriminant analysis (PLS-DA), and linear discriminant analysis (LDA). Overall, the classification accuracy of each algorithm exceeds 92 %, with SVM and PLS-DA having the best classification performance, while K-NN has relatively poor classification performance. In summary, the plastic classification algorithm for small household appliance recycling based on infrared spectroscopy can meet the actual plastic classification needs of plastic recycling plant production lines.

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基于红外光谱的小型家用电器回收塑料光谱分类分析
从小型家用电器中回收塑料对改善环境和解决资源短缺问题具有重要意义,已逐渐成为各国关注的焦点。首先,对不同颜色、氧化程度和阻燃剂的样品进行光谱采集。结果发现,不同颜色和氧化程度的样品表现出不同的反射率,而含有阻燃剂的样品则表现出较小的吸收峰。随后,对光谱进行了预处理和分析,结果表明在不同条件下采集的样品对塑料分类的影响很小。最后,利用支持向量机(SVM)、反向传播神经网络(BP)、k-近邻(k-NN)、偏最小二乘判别分析(PLS-DA)和线性判别分析(LDA)等算法对塑料光谱进行了分类。总体而言,每种算法的分类准确率都超过了 92%,其中 SVM 和 PLS-DA 的分类性能最好,而 K-NN 的分类性能相对较差。综上所述,基于红外光谱的小家电回收塑料分类算法能够满足塑料回收厂生产线的实际塑料分类需求。
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来源期刊
Vibrational Spectroscopy
Vibrational Spectroscopy 化学-分析化学
CiteScore
4.70
自引率
4.00%
发文量
103
审稿时长
52 days
期刊介绍: Vibrational Spectroscopy provides a vehicle for the publication of original research that focuses on vibrational spectroscopy. This covers infrared, near-infrared and Raman spectroscopies and publishes papers dealing with developments in applications, theory, techniques and instrumentation. The topics covered by the journal include: Sampling techniques, Vibrational spectroscopy coupled with separation techniques, Instrumentation (Fourier transform, conventional and laser based), Data manipulation, Spectra-structure correlation and group frequencies. The application areas covered include: Analytical chemistry, Bio-organic and bio-inorganic chemistry, Organic chemistry, Inorganic chemistry, Catalysis, Environmental science, Industrial chemistry, Materials science, Physical chemistry, Polymer science, Process control, Specialized problem solving.
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