A viscosity-soluble type biomimetic self-healing cement slurry system

Abstract

With the development of cementing slurry technology, cementing self-healing has become one of the most effective technologies to prevent and treat oil and gas channeling and improve long-term sealing capacity of cement sheath. To solve the technical problem of annulus oil and gas channeling caused by the long-term sealing failure of cement sheath, this paper researches and develops a kind of viscosity-soluble type biomimetic self-healing cement slurry system from the perspective of chemical biomimetics, based on the technical idea of “prevention before blocking”. Then, the engineering performance of this biomimetic self-healing cement slurry system and the mechanical property of self-healing set cement are evaluated respectively. In addition, the mechanical recovery capacity and permeability reducing rate of the self-healing set cement conserved with methane are evaluated by creating fractures through splitting. Finally, the healing mechanisms of the self-healing cement are analyzed by means of SEM microscopic test and infrared spectrography. And the following research results are obtained. First, the set cement has excellent mechanical property. When the compressive strength decreases by 15 %, the elastic modulus of set cement decreases by 41 %, showing good toughness to play the role of “first prevention”. Second, when meeting hydrocarbon, the damaged set cement is excited to generate a kind of viscosity-soluble type gelatinous ester substance, which re-bonds the skeleton of the set cement. When the self-healing set cement is conserved with methane, its compressive strength recovery rate is up to 94.5 %, bending strength recovery rate is 58.6 %, gas log permeability drops by 99 %, and liquid log permeability drops by 100 %, so as to realize “blocking later”. In conclusion, the viscosity-soluble type biomimetic self-healing cement slurry system can effectively achieve cementing integrity and long-term sealing integrity through self-healing after the damage of cement sheath, which provides a strong technical support for preventing the production safety hazard of sustained casing pressure in oil and gas wells and is beneficial to solve the technical problem of annulus oil and gas channeling caused by long-term sealing failure of cement sheath.