Polarimetric Features of PEPC Polymer Doped with Photoisomerizable SY3 Azodye Chromophore

E. A. Achimova, V. G. Abashkin, A. Yu. Meshalkin, C. S. Losmanschii, V. S. Botnari
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Abstract

Photo-induced anisotropy measurements were carried out in thin films of azopolymers PEPC with Solvent Yellow 3, with the concentrations of 10 and 30 wt % of polymers with azo groups in their side-chain. The experimental dependences of the azimuths of the probe beam at the pump beam angles for samples were studied. The photoinduced dependence of the sample birefringence of the probe beam at the incident polarization angle of the pump beam was carried out by the polarimetric method for the studied samples. The geometric phase of anisotropic carbazole-containing azopolymers, in contrast to the dynamic phase, can be measured by the proposed polarimetric method without involving interferometry methods. This is possible because the geometric phase is not controlled by the difference in optical paths but is the result of a change of polarization inside the films due to photoinduced changes in its spatial structure.

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掺杂了可光异构化的 SY3 叠氮染料发色团的 PEPC 聚合物的偏振特性
摘要采用溶剂黄3对偶氮聚合物PEPC薄膜进行了光致各向异性测量,其中侧链上有偶氮基团的聚合物浓度分别为10%和30%。研究了样品在泵浦光束角处探测光束方位角的实验依赖关系。用偏振法对所研究的样品进行了探针光束在泵浦光入射偏振角处的双折射光致依赖性分析。与动态相相相比,各向异性含咔唑偶氮聚合物的几何相可以用所提出的偏振法测量,而不涉及干涉测量方法。这是可能的,因为几何相位不是由光路的差异控制的,而是由于光诱导其空间结构的变化而引起的膜内偏振变化的结果。
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来源期刊
Surface Engineering and Applied Electrochemistry
Surface Engineering and Applied Electrochemistry Engineering-Industrial and Manufacturing Engineering
CiteScore
1.60
自引率
22.20%
发文量
54
期刊介绍: Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.
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