Recent progress in conjugated polymers composites with metal-organic frameworks as electrode materials for supercapacitors

IF 7.5 Q1 CHEMISTRY, PHYSICAL Applied Surface Science Advances Pub Date : 2023-12-15 DOI:10.1016/j.apsadv.2023.100555
Priya Siwach , Latisha Gaba , Sajjan Dahiya , Rajesh Punia , A.S. Maan , Kuldeep Singh , Anil Ohlan
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Abstract

Extensive research for the advancement of electrode materials with high efficiency and potential for supercapacitors (SCs) has shed light on the role of conjugated polymers (CPs). The outstanding properties of CPs, including controllable electrical conductivity, synthesis feasibility, affordability, substantial porosity, and eco-friendliness, bring them to the forefront of pseudocapacitive electrode materials. This review aims to explore the progress of CPs through their integration with Metal-Organic Frameworks (MOFs). The synergistic effect between CPs and MOFs has garnered significant attention from researchers owing to their special attributes, such as enhanced conductivity, superior cycle stability, improved energy/ power density, mechanical robustness, and large surface area. This review provides valuable insights into the advantages and the latest research endeavors conducted through the integration of CPs and MOFs. The main objective of this survey is to offer a comprehensive discussion of how the incorporation of MOFs can greatly enhance the performance of CPs by effectively mitigating their limitations. Furthermore, the existing challenges and prospective solutions of hybrid CP@MOF materials have been highlighted. By summarizing the cutting-edge developments and emphasizing the scope for innovation, this review paper seeks to inspire further research on CP@MOF composites and provides a pathway toward the commercialization of supercapacitor devices.

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共轭聚合物与金属有机框架复合材料作为超级电容器电极材料的最新进展
对超级电容器(SCs)高效电极材料的广泛研究揭示了共轭聚合物(CPs)的作用。CPs的优异性能,包括电导率可控、合成可行性、价格合理、孔隙度高、生态友好等,使其成为赝电容电极材料的前沿。本文综述了CPs与金属有机框架(MOFs)的结合研究进展。CPs和mof之间的协同效应由于其特殊的属性,如增强的导电性、优异的循环稳定性、改善的能量/功率密度、机械稳健性和大表面积,引起了研究人员的极大关注。本文综述了CPs和MOFs结合的优势和最新的研究成果。本调查的主要目的是提供一个全面的讨论,如何结合mof可以大大提高CPs的性能,有效地减轻其局限性。此外,还强调了混合CP@MOF材料存在的挑战和未来的解决方案。通过总结前沿发展和强调创新的范围,本文旨在启发CP@MOF复合材料的进一步研究,并为超级电容器器件的商业化提供一条途径。
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1.60%
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128
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66 days
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