Рt/SAPO-11 Catalytic Systems Differing in Acidity and Secondary Pore Structure in n-Hexadecane Hydroisomerization

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC Petroleum Chemistry Pub Date : 2023-12-22 DOI:10.1134/S096554412308008X
M. R. Agliullin, D. V. Serebrennikov, A. N. Khazipova, A. I. Malunov, K. I. Dement’ev, B. I. Kutepov
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Abstract

SAPO-11 molecular sieve samples differing in the acid properties, crystal morphology and size, and secondary pore structure characteristics were obtained by crystallization of reaction gels with the SiO2/Al2O3 molar ratios of 0.1 and 0.3, prepared using aluminum isopropoxide or boehmite as an aluminum source. Platinum (0.5 wt %) was deposited onto the molecular sieves prepared, and the catalytic properties of the resulting samples in n-hexadecane hydroisomerization were studied. The hydrocarbon conversion on these samples varies from 76.8 to 87.7 wt %, and the isoparaffin formation selectivity, from 76.7 to 91.2 wt %.

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正十六烷加氢异构化过程中不同酸度和二级孔结构的 Рt/SAPO-11 催化体系
以异丙醇铝或沸石为铝源,通过对 SiO2/Al2O3 摩尔比为 0.1 和 0.3 的反应凝胶进行结晶,得到了在酸性、晶体形貌和尺寸以及二级孔结构特征方面存在差异的 SAPO-11 分子筛样品。在制备的分子筛上沉积了铂(0.5 wt %),并研究了所得样品在正十六烷加氢异构化中的催化特性。这些样品的碳氢化合物转化率为 76.8% 至 87.7%,异链烷烃形成选择性为 76.7% 至 91.2%。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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