Numerical optimization of dielectric properties to achieve process uniformity in capacitively coupled plasma reactors

Ho Jun Kim, Kyungjun Lee, Hwanyeol Park
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Abstract

This paper presents the results of our numerical analysis to optimize the dielectric properties to achieve process uniformity in the thin film deposition process using capacitively coupled plasma. The difference in the plasma density distribution was analyzed by changing the wafer material from silicon to quartz (or Teflon). Similarly, aluminum was compared with aluminum nitride as the electrode material, and the sidewall material was varied from quartz to a perfect dielectric to study the effect on the plasma characteristics. A two-dimensional self-consistent fluid model was used to analyze the spatial distribution of the plasma parameters. In terms of the process conditions, the gas pressure was set to 400 Pa, the input power was fixed to 100 W, and a radio frequency of 13.56 MHz was used. SiH4/Ar was used as the gas mixture, and these conditions were used as input for numerical simulations of the deposition state of the hydrogenated amorphous silicon layer. The radial spatial distribution of plasma parameters was confirmed to be modified by dielectric elements with low dielectric constants regardless of the type of element. Despite the thin wafer thickness, the use of a wafer with low permittivity weakens the electric field near the electrode edge due to the stronger surface charge effect. Additionally, by changing the material of the sidewall to a perfect dielectric, a more uniform distribution of plasma could be obtained. This is achieved as the peak values of the plasma parameters are located away from the wafer edge. Interestingly, the case in which half of the sidewall was specified as comprising a perfect dielectric and the other half quartz had a more uniform distribution than the case in which the sidewalls consisted entirely of a perfect dielectric.
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电介质特性的数值优化,实现电容耦合等离子体反应器的工艺一致性
本文介绍了我们的数值分析结果,该分析旨在优化介电特性,从而在使用电容耦合等离子体的薄膜沉积工艺中实现工艺均匀性。通过将硅片材料改为石英(或聚四氟乙烯),分析了等离子体密度分布的差异。同样,将铝与氮化铝作为电极材料进行了比较,并将侧壁材料从石英改为完美电介质,以研究其对等离子体特性的影响。使用二维自洽流体模型分析了等离子体参数的空间分布。在工艺条件方面,气体压力设定为 400 Pa,输入功率固定为 100 W,无线电频率为 13.56 MHz。SiH4/Ar 被用作混合气体,这些条件被用作氢化非晶硅层沉积状态数值模拟的输入。证实了等离子体参数的径向空间分布被低介电常数的介电元件所改变,而与介电常数的类型无关。尽管硅片厚度很薄,但由于表面电荷效应较强,使用低介电常数的硅片会削弱电极边缘附近的电场。此外,通过将侧壁材料改为完美电介质,可以获得更均匀的等离子体分布。这是因为等离子体参数的峰值远离晶片边缘。有趣的是,与侧壁完全由完美电介质组成的情况相比,一半侧壁指定由完美电介质组成,另一半由石英组成的情况下,等离子体的分布更加均匀。
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