A review on the influence of various metal oxide nanoparticles on structural, morphological, optical, thermal and electrical properties of PVA/PVP blends

IF 3.6 4区材料科学 Q2 MATERIALS SCIENCE, COMPOSITES Journal of Thermoplastic Composite Materials Pub Date : 2023-12-15 DOI:10.1177/08927057231222833

K. Meera, M. T. Ramesan

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Abstract

Biopolymer blend based nanocomposites have been interestingly investigated by researchers to achieve advanced composite functional materials that are environmentally amicable. Among the varieties of biopolymers, widespread attention has been given to polyvinyl alcohol (PVA) and polyvinyl pyrrolidone (PVP) owing to their interesting properties like water solubility, biodegradability, biocompatibility and non-toxicity. PVA and PVP form a completely miscible blend at all compositions as both the polymers are rich in a variety of functional groups that permit effective intermolecular interactions between the polymers as well as with filler. PVA/PVP blend exhibits excellent dopant sensitive properties also. Metal oxide nanoparticles (MONPs) have made a prominent place in the area of scientific and technological research due to their unique chemical and physical properties. Doping with MONPs enhances the properties of the PVA/PVP blend matrix and the resulting PVA/PVP/MONP polymer nanocomposites are suitable for multifunctional purposes. This review mainly focused on the influence of various MONPs such as ZnO, CuO, Al2O3, ZrO2, MnO, SnO, MgO, TiO2, etc. in the structural, morphological, thermal, optical and electrical properties of PVA/PVP blend as well as its applications in various fields.

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综述各种金属氧化物纳米粒子对 PVA/PVP 共混物的结构、形态、光学、热学和电学特性的影响

研究人员对基于生物聚合物共混物的纳米复合材料进行了有趣的研究，以获得对环境无害的先进复合功能材料。在各种生物聚合物中，聚乙烯醇（PVA）和聚乙烯吡咯烷酮（PVP）因其水溶性、生物降解性、生物相容性和无毒性等有趣的特性而受到广泛关注。PVA 和 PVP 在所有成分中都能形成完全混溶的混合物，因为这两种聚合物都富含各种官能团，使聚合物之间以及与填料之间的分子间相互作用更为有效。PVA/PVP 共混物还具有出色的掺杂剂敏感特性。金属氧化物纳米粒子（MONPs）因其独特的化学和物理特性，在科技研究领域占据了重要地位。掺入 MONPs 可增强 PVA/PVP 共混基质的性能，由此制得的 PVA/PVP/MONP 聚合物纳米复合材料适用于多功能用途。本综述主要关注各种 MONPs（如 ZnO、CuO、Al2O3、ZrO2、MnO、SnO、MgO、TiO2 等）对 PVA/PVP 共混物结构、形态、热学、光学和电学性能的影响及其在各个领域的应用。

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来源期刊

Journal of Thermoplastic Composite Materials 工程技术-材料科学：复合

CiteScore

8.00

自引率

18.20%

发文量

104

审稿时长

5.9 months

期刊介绍： The Journal of Thermoplastic Composite Materials is a fully peer-reviewed international journal that publishes original research and review articles on polymers, nanocomposites, and particulate-, discontinuous-, and continuous-fiber-reinforced materials in the areas of processing, materials science, mechanics, durability, design, non destructive evaluation and manufacturing science. This journal is a member of the Committee on Publication Ethics (COPE).