Treatment of Contaminated Collected Wastwater at Petroleum Fuel Filling Stations for Using as Make Up Water for Cooling Tower in Petroleum Refineries

Thabit A. Ahmed, Saba S. Ayob, Mohammed A. Shahatha, Shaymaa R. Khorsheed, Mohammed J. Mohammed
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Abstract

The collection of washing wastewater (oily water) in petroleum service stations represents an environmental problem particularly after the introducing of cars washing stations to the petroleum station site. The generated water from washing and maintenance of the petroleum stations, rain water is collected in the storage tank. This water contains hydrocarbons and suspended solids with high organic load. Discarding this type of water to the water bodies like rivers without treatment causes increasing of pollution. This study aims to manage generated wastewater in petroleum service stations successfully by using methods keeping the source of water and protect the environment from the pollution. Alsmood and Alnaher petroleum stations which are located at the east of Baghdad were taken as case study. A mixed sample of wastewater from both two stations was prepared. The sample was fully tested to study the expected specifications of water.The mixed samle was underwent to many treatement stages(oil skimming,coagulation-flocculation, sand filteration).The oil concentration of the raw smixed sample was decreased from (5% , 50000mg/L) to 1mg/L . The turbidity value was reduced after filteration from 175 to 1.4 NTU and also the total suspended solids(TSS) was decreased from 272 mg/L to 4 mg/L. The chemical oxygen demand (COD) underwent reduction during wastewater treatment from 730 to 44 mg O2 /L . Badse on the research fndings,the proposed scenario to manage the watstewater is installing a wastewater (oily water) treatment plant with 100m3/day capacity next to Aldura refinery in Baghdad to treat the water for reusing application as a make-up water for the cooling towers.
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处理石油燃料加注站收集的受污染废水,将其用作炼油厂冷却塔的补给水
石油服务站清洗废水(含油废水)的收集是一个环境问题,尤其是在石油站引入汽车清洗站之后。石油站清洗和维护产生的水、雨水被收集到储水罐中。这些水含有碳氢化合物和高有机负荷的悬浮固体。不经处理就将这些水丢弃到河流等水体中会导致污染加剧。这项研究的目的是通过使用保持水源的方法成功管理石油服务站产生的废水,保护环境免受污染。研究以位于巴格达东部的 Alsmood 和 Alnaher 加油站为案例。从这两个加油站提取了混合废水样本。混合样本经过了多个处理阶段(撇油、混凝-絮凝、砂滤),原始混合样本的油浓度从(5%,50000 毫克/升)降至 1 毫克/升。过滤后的浊度值从 175 NTU 降至 1.4 NTU,总悬浮固体(TSS)也从 272 mg/L 降至 4 mg/L。在废水处理过程中,化学需氧量(COD)从 730 毫克氧气/升降至 44 毫克氧气/升。根据研究结果,建议的废水处理方案是在巴格达 Aldura 炼油厂旁边安装一个日处理能力为 100 立方米的废水(含油水)处理厂,将废水处理后作为冷却塔的补给水重新使用。
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