40-meter-long REBCO tapes with critical current over 4,000 A/12 mm at 4.2 K and 13 T by advanced MOCVD

IF 5.6 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Superconductivity Pub Date : 2023-12-16 DOI:10.1016/j.supcon.2023.100081
Mahesh Paidpilli , Chirag Goel , Bhabesh Sarangi , Siwei Chen , Eduard Galstyan , Jan Jaroszynski , Griffin Bradford , Dmytro Abraimov , Venkat Selvamanickam
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Abstract

REBa2Cu3O7−δ (REBCO, RE = rare earth) tapes doped with 5% and 15% Zr have been scaled up to lengths more than 40 m in a pilot-scale advanced metal organic chemical vapor deposition (A-MOCVD) tool. The precursor compositions used for the long tapes were guided by a study of the influence of (Ba + dopant)/Cu content on the critical current density (Jc) of 5 and 15 mol.% Hf- and Zr-added tapes at 4.2 K and 13 T. The 40-m-long tapes exhibited a critical current (Ic) over 4,000 A/12 mm at 4.2 K and 13 T as well as over 1,400 A/12 mm at 20 K and 20 T. The critical current densities of a 40-m-long tape doped with 5% Zr at 4.2 K measured at the National High Magnetic Field Laboratory (NHMFL) were > 10 MAcm−2 and >5 MAcm−2 at 14 T and 30 T, respectively, which are over three times those of commercial REBCO tapes. The infield Jc of 5% Zr-added 40-m-long tapes was similar to those of previously-reported high-performance short samples made with 15% Zr or Hf. These results demonstrate the excellent potential of A-MOCVD for manufacturing high Ic REBCO tapes for use in ultrahigh-field magnet applications.

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通过先进的 MOCVD 技术,在 4.2 K 和 13 T 条件下,40 米长的 REBCO 带临界电流超过 4,000 A/12 mm
在中试规模的先进金属有机化学气相沉积(A-MOCVD)工具中,掺杂 5% 和 15% Zr 的 REBa2Cu3O7-δ(REBCO,RE = 稀土)带的长度已超过 40 米。在 4.2 K 和 13 T 条件下,(Ba + 掺杂剂)/Cu 含量对 5 和 15 mol.% Hf- 和 Zr- 添加带的临界电流密度 (Jc) 的影响研究指导了长带所用的前驱体成分。在国家高磁场实验室(NHMFL)测量到的 4.2 K 时掺杂 5% Zr 的 40 m 长磁带在 14 T 和 30 T 时的临界电流密度分别为 10 MAcm-2 和 5 MAcm-2,是商用 REBCO 磁带的三倍多。添加 5% Zr 的 40 m 长胶带的内场 Jc 与之前报道的使用 15% Zr 或 Hf 制成的高性能短样品的内场 Jc 相似。这些结果证明了 A-MOCVD 在制造超高磁场应用中使用的高 Ic REBCO 磁带方面的巨大潜力。
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