Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction
A. V. Romanenko, P. A. Simonov, M. A. Kulagina, S. I. Udalova, I. N. Voropaev, G. A. Bukhtiyarova
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引用次数: 0
Abstract
Results of studying the Pd/C and Pd/O powder catalysts synthesized by the deposition of 0.5 and 1.0 wt % Pd on carbon materials (Sibunit 159k, thermal carbon black T-900, Vulcan XC-72R) and oxide supports (Ox: γ-Al2O3, Cr2O3, Ga2O3, TiO2, Ta2O5, and V2O5, diatomaceous earth FW-70) and their catalytic properties in the partial hydrogenation of sunflower oil were described. Using a Parr fixed-bed reactor, comparative tests of the catalysts in the kinetic mode conducted to determine their activity (SCA, V0) and trans-isomerization selectivity parameters (Str). The effect of the average particle size of supported palladium (dCO) on these parameters in a wide range of dCO values was discussed.
期刊介绍：
The journal covers the following topical areas:
Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
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