Investigation of Corrosion Behavior of Stir-Cast Hybrid Aluminum Composite Reinforced with CeO2 and GNPs Nanoparticles

IF 0.8 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2023-12-29 DOI:10.1134/S2070205123701186
Dinesh Kumar, Surjit Angra, Satnam Singh
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Abstract

This study investigates the corrosion behavior of stir-cast hybrid aluminum composite reinforced with CeO2 and graphene nanoplatelets (GNPs) nanoparticles used as cylinder liner material in the engines (Automotive, aerospace, and aircraft industries). The composites were prepared using the stir-casting technique, and their microstructure and corrosion behavior was evaluated using scanning electron microscopy (SEM) and Potentiodynamic polarization test, respectively. The results showed that the addition of CeO2 and GNPs improved the corrosion resistance of the composites, and the optimal combination of these two nanoparticles was found to be 3 wt % CeO2 and 3 wt % GNPs. The enhanced corrosion resistance was attributed to the formation of a protective layer on the surface of the composite, as well as the effective dispersion and uniform distribution of nanoparticles in the matrix. The 0.031362 was noted as the lowest corrosion rate (mmpy) was noticed in V04 sample at room temperature and at elevated temperatures, the corrosion rate (mmpy) was observed as 0.060081 and 0.063627 at 45 and 75°C, respectively. In the vast majority of the published research publications, either cerium oxide or graphene nanoplatelets were utilized as a single reinforcement or in conjunction with other types of reinforcement such as alumina, silicon carbide, carbon nano-tubes, tungsten carbide, etc, but on the combination of the CeO2 and GNPs as reinforcements have very-2 less literature, with 2 wt % each only. The prepared hybrid aluminum composite (with reinforcing 1 to 3 wt % in Al-6061 alloy) was considered for replacing the cylinder liner material in the piston-cylinder arrangement.

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用 CeO2 和 GNPs 纳米粒子增强的搅拌铸造混合铝复合材料的腐蚀行为研究
摘要 本研究探讨了在发动机(汽车、航空航天和飞机工业)中用作气缸套材料的 CeO2 和石墨烯纳米片 (GNPs) 纳米颗粒增强的搅拌铸造混合铝复合材料的腐蚀行为。复合材料采用搅拌铸造技术制备,并分别使用扫描电子显微镜(SEM)和电位极化测试对其微观结构和腐蚀行为进行了评估。结果表明,CeO2 和 GNPs 的添加提高了复合材料的耐腐蚀性,这两种纳米粒子的最佳组合为 3 wt % CeO2 和 3 wt % GNPs。耐腐蚀性能的增强归功于复合材料表面保护层的形成,以及纳米粒子在基体中的有效分散和均匀分布。室温下,V04 样品的腐蚀速率(mmpy)最低,为 0.031362;在高温下,45°C 和 75°C 的腐蚀速率(mmpy)分别为 0.060081 和 0.063627。在绝大多数已发表的研究论文中,氧化铈或石墨烯纳米片都被用作单一的增强剂或与氧化铝、碳化硅、碳纳米管、碳化钨等其他类型的增强剂结合使用,但将 CeO2 和 GNPs 结合使用作为增强剂的文献却非常少,只有 2 wt %。所制备的混合铝复合材料(在 Al-6061 合金中添加 1 至 3 wt % 的增强材料)被考虑用于在活塞-气缸布置中替代气缸套材料。
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来源期刊
CiteScore
1.90
自引率
18.20%
发文量
90
审稿时长
4-8 weeks
期刊介绍: Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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