TiO2 and CeO2 nanoparticles as lithium complex grease additives for enhanced lubricity

IF 1.5 4区 工程技术 Q3 ENGINEERING, MECHANICAL Industrial Lubrication and Tribology Pub Date : 2024-01-08 DOI:10.1108/ilt-09-2023-0291
Zhicai Du, Qiang He, Hengcheng Wan, Lei Zhang, Zehua Xu, Yuan Xu, Guotao Li
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Abstract

Purpose

This paper aims to improve the tribological properties of lithium complex greases using nanoparticles to investigate the tribological behavior of single additives (nano-TiO2 or nano-CeO2) and composite additives (nano-TiO2–CeO2) in lithium complex greases and to analyze the mechanism of their influence using a variety of characterization tools.

Design/methodology/approach

The morphology and microstructure of the nanoparticles were characterized by scanning electron microscopy and an X-ray diffractometer. The tribological properties of different nanoparticles, as well as compounded nanoparticles as greases, were evaluated. Average friction coefficients and wear diameters were analyzed. Scanning electron microscopy and three-dimensional topography were used to analyze the surface topography of worn steel balls. The elements present on the worn steel balls’ surface were analyzed using energy-dispersive spectroscopy and X-ray photoelectron spectroscopy.

Findings

The results showed that the coefficient of friction (COF) of grease with all three nanoparticles added was low. The grease-containing composite nanoparticles exhibited a lower COF and superior anti-wear properties. The sample displayed its optimal tribological performance when the ratio of TiO2 to CeO2 was 6:4, resulting in a 30.5% reduction in the COF and a 29.2% decrease in wear spot diameter compared to the original grease. Additionally, the roughness of the worn spot surface and the maximum depth of the wear mark were significantly reduced.

Originality/value

The main innovation of this study is the first mixing of nano-TiO2 and nano-CeO2 with different sizes and properties as compound lithium grease additives to significantly enhance the anti-wear and friction reduction properties of this grease. The results of friction experiments with a single additive are used as a basis to explore the synergistic lubrication mechanism of the compounded nanoparticles. This innovative approach provides a new reference and direction for future research and development of grease additives.

Peer review

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-09-2023-0291/

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作为锂复合润滑脂添加剂的 TiO2 和 CeO2 纳米粒子可增强润滑性能
目的 本文旨在利用纳米颗粒改善复合锂基润滑脂的摩擦学性能,研究复合锂基润滑脂中单一添加剂(纳米二氧化钛或纳米二氧化铈)和复合添加剂(纳米二氧化钛-二氧化铈)的摩擦学行为,并利用多种表征工具分析其影响机理。评估了不同纳米颗粒以及作为润滑脂的复合纳米颗粒的摩擦学特性。分析了平均摩擦系数和磨损直径。扫描电子显微镜和三维形貌图用于分析磨损钢球的表面形貌。结果表明,添加了三种纳米颗粒的润滑脂的摩擦系数(COF)较低。含有复合纳米粒子的润滑脂显示出较低的摩擦系数和优异的抗磨损性能。当 TiO2 与 CeO2 的比例为 6:4 时,样品显示出最佳的摩擦学性能,与原始润滑脂相比,COF 降低了 30.5%,磨损点直径减小了 29.2%。本研究的主要创新点是首次将不同尺寸和性质的纳米 TiO2 和纳米 CeO2 混合作为复合锂基润滑脂添加剂,以显著增强该润滑脂的抗磨减摩性能。以单一添加剂的摩擦实验结果为基础,探索了复合纳米粒子的协同润滑机理。这一创新方法为今后润滑脂添加剂的研究和开发提供了新的参考和方向。同行评审本文的同行评审记录可在以下网址查阅:https://publons.com/publon/10.1108/ILT-09-2023-0291/。
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来源期刊
Industrial Lubrication and Tribology
Industrial Lubrication and Tribology 工程技术-工程:机械
CiteScore
3.00
自引率
18.80%
发文量
129
审稿时长
1.9 months
期刊介绍: Industrial Lubrication and Tribology provides a broad coverage of the materials and techniques employed in tribology. It contains a firm technical news element which brings together and promotes best practice in the three disciplines of tribology, which comprise lubrication, wear and friction. ILT also follows the progress of research into advanced lubricants, bearings, seals, gears and related machinery parts, as well as materials selection. A double-blind peer review process involving the editor and other subject experts ensures the content''s validity and relevance.
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