Thermodynamic and kinetic modeling and experiment on plasma ignition of pulverized high-ash coal

Vladimir E. Messerle, Alexandr B. Ustimenko
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Abstract

Solid fuels are relatively inexpensive and widely available, making them an attractive option for energy producers. However, they are currently inefficient in converting heat energy into electricity, and new technological advances are needed to make them more efficient. Plasma ignition and stabilization of pulverized coal flame provides a cost-effective and sustainable approach to boiler start-up and combustion stabilization, avoiding the traditionally used fuel oil or gas. This technology consists of heating the air-coal mixture with electric arc plasma to the temperature of coal devolatilization and partial gasification of the coke residue. Thus, a highly reactive two-component fuel, consisting of combustible gas and coke residue, is obtained from the original coal. In this paper, a comprehensive thermodynamic and kinetic analysis was carried out. A thermodynamic analysis was carried out to study the optimal parameters of plasma ignition and stabilization of combustion of a pulverized fuel flame. Kinetic modeling of the process of plasma ignition and stabilization of combustion of pulverized fuel made it possible to obtain changes in temperatures, velocities and concentrations of high-temperature two-component fuel components along the length of the plasma-fuel system. In experiments on plasma ignition of thermal coal, a stable coal-dust flame was obtained, and its temperature, composition and degree of carbon gasification were determined. Comparison of experimental and calculated data showed satisfactory agreement.

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高灰分煤粉等离子体点火的热力学和动力学建模与实验
固体燃料价格相对低廉,供应广泛,因此对能源生产商来说是一个具有吸引力的选择。然而,目前它们在将热能转化为电能方面效率较低,需要新的技术进步来提高它们的效率。等离子体点火和稳定煤粉火焰为锅炉启动和稳定燃烧提供了一种具有成本效益和可持续发展的方法,避免了传统上使用的燃油或燃气。该技术包括用电弧等离子体将空气-煤混合物加热到煤炭脱碳和焦炭残渣部分气化的温度。这样,就能从原煤中获得由可燃气体和焦炭残渣组成的高活性双组分燃料。本文进行了全面的热力学和动力学分析。通过热力学分析,研究了等离子体点火和稳定煤粉燃料火焰燃烧的最佳参数。对等离子体点火和粉化燃料稳定燃烧过程进行动力学建模,可以获得高温双组分燃料成分沿等离子体-燃料系统长度方向的温度、速度和浓度变化。在热煤的等离子点火实验中,获得了稳定的煤粉火焰,并测定了其温度、成分和碳气化程度。实验数据和计算数据的比较结果表明两者的一致性令人满意。
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