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Offline reinforcement learning for mitigating thermoacoustic instabilities in a laminar premixed flame 用于减轻层流预混火焰热声不稳定性的离线强化学习
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-23 DOI: 10.1016/j.jaecs.2026.100464
Juan Camilo Giraldo Delgado, Qi Wang, S. Mani Sarathy
Thermoacoustic instabilities pose a significant challenge in combustion applications, leading to potential damage to rocket engines and gas turbines. Among various mitigation strategies, active control has been explored as a mean to decouple acoustics from heat release in combustion systems. Due to the highly nonlinear nature of thermoacoustic instabilities, machine learning methodologies have gained attention to enhance active control strategies. In particular, prior studies have shown that classical phase-shift control can be improved by adapting its parameters using Reinforcement Learning (RL). In this study, we investigated the application of Offline RL to leverage existing datasets for mitigating thermoacoustic instabilities in a laminar premixed flame. The methodology uses data collected from a closed-loop experimental setup operating under a phase-shift control strategy. The gain and time delay were recorded, and Implicit Q Learning (IQL) was then used to train a neural network (actor) to determine these parameters based on observations of chemiluminescence and pressure fluctuations in the flame. The training procedure was conducted offline, and upon experimental deployment, the trained neural network successfully reduced thermoacoustic instabilities. These results highlight the potential of Offline RL for combustion control applications.
热声不稳定性对燃烧应用提出了重大挑战,导致火箭发动机和燃气轮机的潜在损坏。在各种缓解策略中,主动控制已被探索作为将燃烧系统中的热量释放与声学分离的手段。由于热声不稳定性的高度非线性性质,机器学习方法已引起人们的关注,以增强主动控制策略。特别是,先前的研究表明,经典相移控制可以通过使用强化学习(RL)调整其参数来改进。在这项研究中,我们研究了离线RL的应用,以利用现有数据集来减轻层流预混火焰中的热声不稳定性。该方法使用从闭环实验装置收集的数据,在相移控制策略下运行。记录增益和时间延迟,然后使用内隐Q学习(IQL)来训练神经网络(actor),根据对火焰化学发光和压力波动的观察来确定这些参数。训练过程是离线进行的,经过实验部署,训练后的神经网络成功地降低了热声不稳定性。这些结果突出了离线RL在燃烧控制应用中的潜力。
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引用次数: 0
Radiative characteristics of premixed ammonia-hydrogen and cracked ammonia swirling flames 氨氢预混火焰和裂解氨旋流火焰的辐射特性
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-21 DOI: 10.1016/j.jaecs.2026.100465
Daisuke Sato , Jordan Davies , Syed Mashruk , Agustin Valera-Medina , Ryoichi Kurose
Renewably produced ammonia does not emit CO2 with combustion. Therefore, numerous studies have been conducted in recent years to utilise ammonia as a carbon free fuel. However, there is limited previous knowledge regarding the radiation characteristics of ammonia blend combustion. In this study, radiation characteristics are investigated for 15 kW premixed swirling flames of NH3/H2 (70/30) and 20% cracked NH3, which have been frequent targets of recent research, with equivalence ratios varying from 0.6 ≤ Φ ≤ 1.4. Specifically, water radiation (wavelength 2.7 μm), which is the main radiation source, is measured using an infrared spectrometer. Additionally, radiation emission and absorption in the combustor are evaluated theoretically using H2O exhaust gas concentrations and temperature measurement data. The results suggest that radiation changes due to equivalence ratio variations are gradual on the rich side, showing different trends compared to the lean side. Furthermore, radiation attenuation in the combustor become active around Φ = 0.9. This suggests that when considering radiation in ammonia blend combustion, not only the blend composition but also equivalence ratio conditions must be carefully considered. In addition, radiative heat fluxes were analysed for three blends (NH3/H2, pure NH3, and cracked NH3) at Φ = 1.0, suggesting no significant differences in radiative heat flux among these blends. These research findings provide valuable insights for future combustor designs using ammonia blend fuels.
可再生生产的氨在燃烧时不会排放二氧化碳。因此,近年来进行了大量的研究,以利用氨作为无碳燃料。然而,关于氨混合燃烧的辐射特性,以前的知识有限。在本研究中,研究了最近研究频繁的NH3/H2(70/30)和20%裂解NH3的15 kW预混旋转火焰的辐射特性,等效比为0.6≤Φ≤1.4。其中,主要辐射源水辐射(波长2.7 μm)采用红外光谱仪测量。此外,利用H2O废气浓度和温度测量数据对燃烧室的辐射发射和吸收进行了理论评估。结果表明,由于等效比变化引起的辐射变化在富侧是渐进的,与贫侧相比表现出不同的趋势。此外,燃烧室内的辐射衰减在Φ = 0.9左右变得活跃。这说明在考虑氨共混燃烧中的辐射时,不仅要考虑共混物的组成,还要考虑当量比条件。此外,在Φ = 1.0时,对NH3/H2、纯NH3和裂解NH3共混物的辐射热流密度进行了分析,结果表明,三种共混物的辐射热流密度无显著差异。这些研究结果为未来使用氨混合燃料的燃烧器设计提供了有价值的见解。
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引用次数: 0
Evaluating the thermal response of large-scale decking assemblies exposed to firebrand piles 大型甲板组件暴露于燃烧桩的热响应评估
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-15 DOI: 10.1016/j.jaecs.2026.100463
Mohamed E. Mohamed , Trent D. Penman , Jacques De Beer , Stanislav I. Stoliarov , Gavin P. Horn , Alexander I. Filkov
Firebrand accumulation in the form of piles significantly contribute to structural losses in the Wildland-Urban Interface. Decking materials may be particularly vulnerable to ignition from firebrand piles. However, large-scale studies replicating real-world conditions are still lacking. This study investigates the observed thermal response of Pressure Treated Wood (PTW) and Trex Enhance (Trex) composite decking under exposure to 8 grams firebrand piles (10 cm × 5 cm x 2 cm) at large-scale decking assembly (60 cm × 60 cm). Experimental conditions involved different constant wind speed (1.4 m s-1 and 2.7 m s-1); moisture content (MC) of tested materials (PTW: 26% and 7%; Trex: <1%); and firebrand pile orientation (0°: 10 cm side parallel to airflow; and 90°: 10 cm side perpendicular to airflow). For PTW experiments, three key events were observed: 1) Burn-through: when the samples experienced vertical propagation until a glowing-edged opening >5 mm appeared at the back surface; 2) Back surface flaming ignition: when transition from smouldering to intense flaming ignition took place at the back surface; and 3) Back surface re-ignition: when flaming ignition appeared second time at the back surface but at lower intensity. For PTW, the higher wind speed (2.7 m s-1) was the dominant factor associated with significantly increased likelihood of burn-through and was a necessary factor in inducing back surface flaming. The low MC (7%) also increased the propensity for burn-through and back surface flaming, though to a lesser extent. Although firebrand pile orientation showed insignificant impact on the overall thermal response, it still played a critical role. The 90° orientation increased the burn-through propensity, while 0° orientation displayed a greater tendency for back surface flaming and its associated characteristics. Compared to PTW, Trex exhibited considerably lower combustion intensity and duration, with no observations of burn-through or back surface flaming in any experiment.
以桩的形式堆积的火种对荒地-城市界面的结构损失起着重要的作用。铺装材料可能特别容易被火把桩点燃。然而,复制现实世界条件的大规模研究仍然缺乏。本研究调查了压力处理木材(PTW)和Trex Enhance (Trex)复合甲板在暴露于8克火焰桩(10厘米× 5厘米× 2厘米)下的热响应,并进行了大规模甲板组装(60厘米× 60厘米)。实验条件包括不同恒定风速(1.4 m s-1和2.7 m s-1);测试材料的含水率(MC) (PTW: 26%和7%;Trex: 1%);火种桩方向(0°:10 cm侧与气流平行;90°:10 cm侧与气流垂直)。对于PTW实验,观察到三个关键事件:1)烧透:当样品经历垂直传播时,直到背面出现5 mm的发光边缘开口;2)后表面燃烧着火:当后表面由闷烧过渡到强烈燃烧着火时;3)后表面重燃:后表面出现第二次火焰点火,但强度较低。对于PTW,较高的风速(2.7 m s-1)是显著增加烧透可能性的主导因素,也是诱发后表面燃烧的必要因素。低MC(7%)也增加了烧透和背面燃烧的倾向,尽管程度较小。火种桩取向对整体热响应的影响不显著,但仍发挥着关键作用。90°取向增加了烧透倾向,而0°取向对后表面燃烧及其相关特征表现出更大的倾向。与PTW相比,Trex表现出相当低的燃烧强度和持续时间,在任何实验中都没有观察到烧透或背面燃烧。
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引用次数: 0
Influence of ethanol-blended B7-diesel on in-cylinder combustion characteristic, engine thermal efficiency and emission of a 3L-compression ignition engine 乙醇-混合b7 -柴油对3l压缩点火发动机缸内燃烧特性、发动机热效率和排放的影响
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-12 DOI: 10.1016/j.jaecs.2026.100461
Teerapat Suteerapongpun , Poonnut Thaeviriyakul , Watanyoo Phairote , Peerawat Saisirirat , Watcharin Po-ngaen , Hidenori Kosaka , Preechar Karin
This study investigated the effects of blending weight ratio of 5% and 10% ethanol (B7E5 and B7E10) with standard B7-diesel on the performance, combustion, and emission characteristics of a light-duty common-rail diesel engine. The engine was tested on a dynamometer across various speeds (1600–2000 rpm) and loads (84 and 112 Nm) to analyze in-cylinder pressure, thermal efficiencies, and exhaust emissions. Results indicated significant emission benefits, especially at high loads. The B7E10 blend reduced smoke intensity by approximately 75% and carbon dioxide emissions by 34% compared to the baseline B7. The performance analysis revealed a critical trade-off associated with the ethanol blends: while the inherent oxygen content in ethanol significantly improved the indicated thermal efficiency (ITE) through enhanced combustion, its lower viscosity simultaneously led to increased frictional losses. Consequently, these competing effects resulted in only a modest improvement in brake thermal efficiency (BTE) and comparable brake-specific energy consumption (BSEC) compared to the baseline B7. The primary objective is to identify the benefits and trade-offs associated with ethanol blending in biodiesel-based diesel fuels that are compatible with existing diesel vehicles.
本试验研究了5%和10%乙醇(B7E5和B7E10)与标准b7柴油混合重量比对轻型共轨柴油机性能、燃烧和排放特性的影响。发动机在不同转速(1600-2000 rpm)和负载(84和112 Nm)下进行了测试,以分析缸内压力、热效率和废气排放。结果表明显著的排放效益,特别是在高负荷下。与基准B7相比,B7E10混合物减少了约75%的烟雾强度和34%的二氧化碳排放量。性能分析揭示了与乙醇混合物相关的关键权衡:虽然乙醇中的固有氧含量通过增强燃烧显着提高了指示热效率(ITE),但其较低的粘度同时导致摩擦损失增加。因此,与基线B7相比,这些竞争效应仅导致制动热效率(BTE)和可比制动特定能耗(BSEC)的适度改善。主要目标是确定与生物柴油为基础的柴油燃料中乙醇混合与现有柴油车辆兼容的好处和权衡。
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引用次数: 0
On the application of planar laser Rayleigh scattering imaging to Ethylene-air detonations at normal atmospheric conditions 平面激光瑞利散射成像在正常大气条件下乙炔空气爆轰中的应用
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1016/j.jaecs.2025.100454
Nicholas Rock , Mateo Gomez , Aaron W. Skiba
Detonation-based technologies have been developed primarily by evaluating different design concepts using global performance metrics (e.g., wave speeds and thrust output). However, several technical challenges, which may require a physics-based development approach to mitigate or resolve, continue to hinder these systems. Unfortunately, the most commonly used tools for characterizing the physics of detonations (i.e., cell size measurements, empirical correlations, and predictive models) do not typically provide enough detailed information to make a significant impact on the development of detonation-based technologies. Therefore, this study demonstrates the use of planar laser Rayleigh scattering (PLRS) imaging to acquire highly resolved data from ethylene-air detonations produced at atmospheric conditions. In particular, the PLRS images enable rare measurements of induction zone regions and allow the details of a detonation’s underlying structure to be visualized in great detail. The accuracy of the induction zone length measurements is assessed via a systematic numerical analysis involving the simulation of laser Rayleigh scattering (LRS) signals from one-dimensional (1-D) ZND results. The numerical results were quantitatively compared to measured LRS signal levels, their spatial gradients, and induction zone lengths at local wave speeds estimated from high-speed (MHz) chemiluminescence imaging. Varying levels of agreement between the measured and calculated results are observed, with the best agreement achieved for detonations propagating at or faster than the CJ speed. Beyond the measured results, this manuscript clearly highlights the benefits, challenges, and future potential of applying PLRS imaging to detonations.
基于爆炸的技术主要是通过使用全局性能指标(例如波速和推力输出)评估不同的设计概念而开发的。然而,一些可能需要基于物理的开发方法来缓解或解决的技术挑战仍然阻碍着这些系统的发展。不幸的是,用于描述爆炸物理特性的最常用工具(即,细胞尺寸测量,经验相关性和预测模型)通常不能提供足够详细的信息,无法对基于爆炸的技术的发展产生重大影响。因此,本研究展示了使用平面激光瑞利散射(PLRS)成像来获取大气条件下产生的乙烯空气爆炸的高分辨率数据。特别是,PLRS图像能够对感应区区域进行罕见的测量,并可以非常详细地可视化爆炸的底层结构细节。通过系统的数值分析,对激光瑞利散射(LRS)信号的一维ZND结果进行模拟,评估了感应区长度测量的准确性。数值结果与测量的LRS信号电平、空间梯度和高速(MHz)化学发光成像估计的局域波速下的感应区长度进行了定量比较。测量结果和计算结果之间的一致性程度不同,在以CJ速度或更快的速度传播的爆炸中达到了最佳一致性。除了测量结果,这份手稿清楚地强调了将PLRS成像应用于爆炸的好处、挑战和未来潜力。
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引用次数: 0
A modeling study on the combustion characteristics of alcohol/diesel dual fuel counterflow flame 酒精/柴油双燃料逆流火焰燃烧特性的建模研究
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1016/j.jaecs.2026.100460
Pourya Rahnama , Ricardo Novella , Bart Somers
This study combines a 0D Well Stirred Reactor (WSR), 1D counterflow flame, experimental data, and a 1D gas dynamic model to create an integrated modeling tool to study the dual fuel combustion behavior in engine-relevant conditions, fueled with E85 and diesel fuels. First, the performance of a reduced chemical kinetic mechanism is studied, and the most important reactions are identified. Subsequently, the validated mechanism is utilized to investigate ignition and flame propagation characteristics, and to analyze the combustion mode in different thermal and compositional stratification levels. The results reveal that under the studied operating conditions, auto-ignition of the background mixture was unlikely due to long ignition delay times compared to experimental combustion durations. Instead, the combustion mode is more of a partially premixed flame and diffusive combustion influenced by reactivity and thermal stratification. The effects of thermal stratification revealed that at higher temperatures of the background mixture, the location of the most reactive mixture fractions moves to the richer sides. Notably, low-temperature ignition behavior reflects the existence of cool flame chemistry near the stoichiometric zone, where intermediate species like formaldehyde form before full heat release occurs. When the oxidizer temperature increases further, a secondary, most reactive mixture fraction can be observed on the oxidizer (lean) side. Temperature and heat release rate profiles also revealed that at lower oxidizer temperatures, the heat release rate shows more traditional diffusive combustion behavior. However, at elevated temperatures, the secondary heat release rate, which corresponds to flame propagation, becomes more prominent. Increasing the ratio of E85 to diesel also influences the partially premixed flame propagation and its heat release. When the oxidizer temperature or E85 content is increased, the location of the secondary heat release moves further away to the oxidizer side, away from the stoichiometric region.
本研究结合0D搅拌釜(WSR)、一维逆流火焰、实验数据和一维气体动力学模型,创建了一个集成的建模工具,研究了在发动机相关条件下,以E85和柴油为燃料的双燃料燃烧行为。首先,研究了还原化学动力学机理的性能,并确定了最重要的反应。随后,利用验证的机理研究了燃烧和火焰传播特性,并分析了不同热成分分层水平下的燃烧模式。结果表明,在实验条件下,由于点火延迟时间较长,本底混合气不可能发生自燃。相反,燃烧模式更多是部分预混火焰和受反应性和热分层影响的扩散燃烧。热分层的影响表明,在背景混合物的较高温度下,最活跃的混合物馏分的位置向较富的一侧移动。值得注意的是,低温点火行为反映了在化学计量区附近存在冷火焰化学,其中甲醛等中间物质在完全放热发生之前就形成了。当氧化剂温度进一步升高时,在氧化剂(贫)侧可以观察到二次的,最活泼的混合物馏分。温度和放热速率曲线还表明,在较低的氧化剂温度下,放热速率表现出更传统的扩散燃烧行为。然而,在较高的温度下,与火焰传播相对应的二次热释放率变得更加突出。增加E85与柴油的比例也会影响部分预混火焰的传播和热量释放。当氧化剂温度或E85含量增加时,二次热释放的位置进一步向氧化剂一侧移动,远离化学计量区。
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引用次数: 0
Monitoring thermoacoustic instability: A comparative analysis of feature-based and end-to-end deep learning approaches 监测热声不稳定性:基于特征和端到端深度学习方法的比较分析
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1016/j.jaecs.2026.100459
Jikang Wang , Yichen Wang, Yupeng Qin, Xuan Lv
This paper compares two data-driven frameworks for monitoring thermoacoustic instability (TAI) in a gas turbine combustor. A conventional machine learning approach using handcrafted features is contrasted with an end-to-end deep learning method employing a convolutional autoencoder (CNN-AE). Both frameworks generate a continuous stability index to quantify the transition from stable to unstable states. Using experimental data, both indices successfully track the entire dynamic evolution, including intermittent precursors. Critically, the CNN-AE autonomously learns a physically meaningful latent space. Visualizing this space reveals the system’s trajectory, showing a clear transition from a disordered attractor (combustion noise) to well-defined limit cycles (instability) through distinct topological shifts. The study demonstrates that deep representation learning not only automates monitoring but also provides a powerful tool for uncovering the underlying nonlinear dynamics of TAI.
本文比较了两种数据驱动的燃气轮机燃烧室热声不稳定性监测框架。使用手工特征的传统机器学习方法与使用卷积自编码器(CNN-AE)的端到端深度学习方法进行了对比。两个框架都生成一个连续的稳定性指数来量化从稳定状态到不稳定状态的转变。利用实验数据,这两个指标都成功地跟踪了整个动态演变,包括间歇性前驱。关键是,CNN-AE自主学习物理上有意义的潜在空间。可视化这个空间揭示了系统的轨迹,显示了从无序吸引子(燃烧噪声)到明确定义的极限环(不稳定性)通过不同的拓扑位移的清晰过渡。研究表明,深度表征学习不仅可以自动化监测,而且为揭示TAI潜在的非线性动力学提供了强大的工具。
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引用次数: 0
Nano-sized boron composites energetic materials: Preparation, combustion and mechanism 纳米硼复合含能材料:制备、燃烧及机理
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-05 DOI: 10.1016/j.jaecs.2026.100458
Mingyu Li , Ruixiao Li , Vladimir Zarko , Richard A. Yetter , Zhongyue Zhou , Weiqiang Pang
Nano-sized boron (nB)-based composite energetic materials (CEMs) are an emerging class of high-energy-density fuels with excellent combustion performance, offering broad potential applications in space propulsion and explosives. In this paper, we review the various preparation techniques for nB-based CEMs (comparing their respective advantages and limitations) and discuss the combustion characteristics and reaction mechanisms of these materials, while also surveying current development trends and future challenges. Recent findings show that incorporating nB significantly improves the ignition characteristics, burning rates, and overall energy release efficiency of B-based energetic formulations. In particular, nB-based composites exhibit faster reaction kinetics, higher energy release rates, and greater gas generation than their micro-sized boron (μB) counterparts. These enhancements underscore the promise of nB-based CEMs for next-generation propellants, explosives, and pyrotechnics, and existing research has already laid a solid foundation for further progress in designing such advanced energetic systems.
纳米级硼基复合含能材料(CEMs)是一类新兴的高能量密度燃料,具有优异的燃烧性能,在空间推进和炸药领域具有广阔的应用前景。本文综述了铌基CEMs的各种制备技术(比较了各自的优点和局限性),讨论了这些材料的燃烧特性和反应机理,同时展望了当前的发展趋势和未来的挑战。最近的研究表明,加入nB显著改善了b基含能配方的点火特性、燃烧速率和整体能量释放效率。特别是,与微尺寸硼(μB)相比,硼基复合材料表现出更快的反应动力学、更高的能量释放率和更多的气体生成。这些增强强调了基于铌的CEMs用于下一代推进剂、炸药和烟火的前景,现有的研究已经为设计这种先进的高能系统的进一步进展奠定了坚实的基础。
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引用次数: 0
Generating a simplified reaction model for methane and natural gas combustion using a genetic algorithm 利用遗传算法生成甲烷和天然气燃烧的简化反应模型
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-01 DOI: 10.1016/j.jaecs.2026.100457
Márton Kovács , Kaito Hirose , Koji Shimoyama , Hisashi Nakamura
A methodology is presented to develop compact, high-fidelity simplified reaction models for hydrocarbon combustion using virtual species and simplified reaction pathways, with rate parameters optimized via a genetic algorithm (GA). The method was applied to methane and natural gas combustion, targeting key combustion properties: ignition delay times (IDT) and laminar burning velocities (LBV). The approach combines a detailed H2/CO core with virtual reactions representing the main fuel oxidation pathways through fuel, fuel radical, and aldehyde virtual species. For natural gas, fuel components were lumped, and averaged thermodynamic properties were assigned to the virtual species. The optimization process produced simplified models with 14 species and 57 reactions, which could accurately reproduce the IDT and LBV simulation results of the AramcoMech 3.0 detailed model across a wide range of equivalence ratios and temperatures. The mean absolute deviations for all test conditions were 11.9% for IDT and 2.5% for LBV in methane, and 10.5% for IDT and 1.4% for LBV in natural gas simulations. The models could capture the tendency differences between methane/air and natural gas/air mixtures in ignition characteristics while preserving the similarities in flame propagation. The proposed method offers a practical alternative to conventional reduction techniques, enabling the generation of simple yet accurate reaction models suitable for CFD simulations in practical combustors with significantly reduced computational cost.
本文提出了一种利用虚拟物质和简化反应路径建立紧凑、高保真的碳氢化合物燃烧简化反应模型的方法,并通过遗传算法(GA)优化速率参数。该方法应用于甲烷和天然气燃烧,针对关键的燃烧特性:点火延迟时间(IDT)和层流燃烧速度(LBV)。该方法结合了详细的H2/CO核心和通过燃料、燃料自由基和醛虚拟物质代表主要燃料氧化途径的虚拟反应。对于天然气,燃料成分被集中,平均热力学性质被分配给虚拟物种。优化过程得到了包含14种反应和57种反应的简化模型,该模型可以在较宽的当量比和温度范围内准确再现AramcoMech 3.0详细模型的IDT和LBV模拟结果。所有测试条件的平均绝对偏差在甲烷中IDT为11.9%,LBV为2.5%,在天然气中IDT为10.5%,LBV为1.4%。该模型可以捕捉甲烷/空气和天然气/空气混合物在点火特性上的趋势差异,同时保留火焰传播的相似性。该方法为传统的还原技术提供了一种实用的替代方案,能够生成简单而准确的反应模型,适用于实际燃烧室的CFD模拟,同时大大降低了计算成本。
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引用次数: 0
A review of municipal solid waste gasification for hydrogen production: Influencing factors, novel technologies, and engineering prospects 城市生活垃圾气化制氢研究进展:影响因素、新技术及工程前景
IF 5 Q2 ENERGY & FUELS Pub Date : 2026-01-01 DOI: 10.1016/j.jaecs.2026.100456
Yongfeng Jiang , Zixuan Yuan , Hao Jiang, Hao Song, Qiang Hu, Jiageng Xia, Haiping Yang, Hanping Chen
The rapid growth of municipal solid waste (MSW) has posed severe environmental challenges, making its safe and resource-efficient disposal crucial for urban sustainable development. Gasification technology offers a promising route for the high-value utilization of MSW by converting it into hydrogen-rich syngas that can be used for power generation, heating, or the production of high-purity H2 fuels. However, the heterogeneous and variable composition of MSW complicates gasification, while the coupled effects of operating parameters on H2 formation remain insufficiently understood. Moreover, a systematic understanding that integrates feedstock characteristics, process optimization, and emerging gasification technologies for efficient H2 generation is still lacking. Therefore, this review systematically summarizes the fundamental characteristics of MSW, the pyrolysis and gasification behaviors of MSW and products characteristics. Key process parameters affecting hydrogen production, including gasifying agents, reaction temperature, residence time, and catalyst type, are critically analyzed. In addition, recent advances in novel heating-assisted gasification technologies, including plasma, Joule heating, electromagnetic induction heating, and microwave heating, are reviewed, together with novel processes such as chemical looping gasification. Finally, large-scale industrial applications of MSW gasification and the recent syngas purification methods for pure H2 production are summarized, followed by an outlook on the future development trends and research priorities for MSW gasification toward sustainable hydrogen production. This review is expected to provide valuable guidance for the process optimization, development of novel gasification technologies, and engineering application of MSW gasification technology for hydrogen production.
城市生活垃圾的快速增长带来了严峻的环境挑战,城市生活垃圾的安全高效处理对城市可持续发展至关重要。气化技术为城市生活垃圾的高价值利用提供了一条有前途的途径,将其转化为富氢合成气,可用于发电、供暖或生产高纯度的H2燃料。然而,生活垃圾的异质性和可变组成使气化变得复杂,而操作参数对H2生成的耦合影响仍未充分了解。此外,还缺乏将原料特性、工艺优化和新兴气化技术整合起来的系统理解,以实现高效制氢。因此,本文系统地总结了城市生活垃圾的基本特征、城市生活垃圾的热解气化行为及产品特征。对影响制氢的关键工艺参数,包括气化剂、反应温度、停留时间和催化剂类型进行了严格分析。此外,还综述了新型加热辅助气化技术的最新进展,包括等离子体加热、焦耳加热、电磁感应加热和微波加热,以及化学环气化等新工艺。最后,总结了城市生活垃圾气化的大规模工业应用以及近年来用于纯氢气生产的合成气净化方法,展望了城市生活垃圾气化可持续制氢的未来发展趋势和研究重点。本文综述将为城市生活垃圾制氢工艺优化、新型气化技术开发及工程应用提供有价值的指导。
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Applications in Energy and Combustion Science
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