WASTE LEMON PEEL AS A CIRCULAR SOLUTION FOR THE REMEDIATION OF LEAD-CONTAMINATED SLUDGE FOR LAND APPLICATION

Chinonye Duru, Fatima Badiru Ibrahim, Aliyu Adamu Dandajeh
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Abstract

Lead-contaminated sludge is a major environmental concern, as land application of this material can contaminate surfaces with toxic heavy metals. To address this, a novel approach to utilizing waste lemon peel (WLP) for the remediation of lead-contaminated sludge for land application with the circular economy in perspective is presented. The WLP was collected from local producers and characterized using Fourier transform infrared (FTIR) spectroscopy to determine the functional groups present. The hydroxyl, carboxyl, ether, and amide groups are the main functional groups in the sample and they have been identified as potential sites responsible for binding heavy metal ions to the biomass. The sludge samples were collected from the Ahmadu Bello University Water treatment plant and analyzed for contamination. The effects of WLP on the lead sorption were investigated using batch experiments. The results indicated that lead sorption onto the WLP was significantly as high as 90.5%. The WLP was found to effectively reduce the lead from the contaminated sludge. This study aimed to identify the capability of WLP as a low-cost and sustainable material for the remediation of lead-contaminated sludge for land application, indicating the potential for waste materials to be utilized in the circular economy. The Material Circularity Indicator of 0.835 indicated a highly circular system.
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将废柠檬皮作为一种循环解决方案,用于修复土地应用中受铅污染的污泥
受铅污染的污泥是一个主要的环境问题,因为这种材料的土地应用会使表面受到有毒重金属的污染。为解决这一问题,本论文从循环经济的角度出发,介绍了一种利用废弃柠檬皮(WLP)修复受铅污染污泥的新方法。废柠檬皮是从当地生产商处收集的,并利用傅立叶变换红外光谱(FTIR)来确定其中的官能团。羟基、羧基、醚基和酰胺基是样本中的主要官能团,它们被确定为将重金属离子与生物质结合的潜在位点。 污泥样本从艾哈迈杜-贝洛大学水处理厂收集并进行污染分析。通过批量实验研究了 WLP 对铅吸附的影响。结果表明,WLP 对铅的吸附率高达 90.5%。研究发现,WLP 能有效减少受污染污泥中的铅含量。这项研究旨在确定 WLP 作为一种低成本和可持续材料的能力,以修复受铅污染的污泥,并将其用于土地应用,这表明废物材料在循环经济中的利用潜力。材料循环性指标为 0.835,表明这是一个高度循环的系统。
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