Dimensionless Number Group Analysis of Surface-Treated Powders

Powders Pub Date : 2023-12-13 DOI:10.3390/powders2040047
B. Ludwig
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Abstract

Modeling powder properties remains a complex and difficult area of study because particulate materials can behave differently under variable conditions based on their bulk and surface-level properties. The research presented in this manuscript was designed to support the fundamental understanding of powder systems by joining experimental and theoretical calculations of dimensionless numbers groups for design purposes. In order to do so, this work focused on two critical variables to better understand fluidization design: physical and chemical surface properties. To better resolve the influence of surface properties, surface-treated powders were used. Five different powder samples of varying particle size distribution were characterized using physical property measurements, including pressure drop profiles to obtain the minimum fluidization velocity, density measurements, and particle sizing. Using theoretical equations, the minimum fluidization velocity was also calculated to compare with those obtained experimentally and determine typical dimensionless number groups used in bulk handling system design. The results showed that the theoretically determined values were lower than those calculated using the experimentally umf. In the case of the Reynolds number, the experimental values were 3–20% higher than the theoretical values, which is an important distinction for designing conveying systems and pipeline flow. Similar results were observed for the theoretical and experimental Froude numbers, indicating an important dependence on the cohesive properties of the particle interactions. Additional dimensionless number groups were considered, including the granular bond number and flow factors. To investigate the influence of surface forces, Hamaker constants were utilized for alumina and polydimethylsiloxane in the calculation of the granular bond number. A lower granular bond was observed with a decrease in the Hamaker constant for PDMS, suggesting that the surface forces would be lower for our surface-treated powders.
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表面处理粉末的无量纲数组分析
粉末特性建模仍然是一个复杂而困难的研究领域,因为颗粒材料在不同条件下的表现会因其体积和表面特性而不同。本手稿中介绍的研究旨在通过将用于设计目的的无量纲数字组的实验和理论计算结合起来,为从根本上理解粉末系统提供支持。为此,这项工作侧重于两个关键变量,以更好地理解流化设计:物理和化学表面特性。为了更好地分析表面特性的影响,我们使用了经过表面处理的粉末。通过物理特性测量,包括获得最小流化速度的压降曲线、密度测定和颗粒大小测量,对五种不同粒度分布的粉末样品进行了表征。还利用理论方程计算了最小流化速度,以便与实验得出的结果进行比较,并确定散料处理系统设计中使用的典型无量纲数组。结果表明,理论确定的数值低于使用实验得出的 umf 计算得出的数值。就雷诺数而言,实验值比理论值高出 3-20%,这对于设计输送系统和管道流动来说是一个重要的区别。在理论和实验弗劳德数方面也观察到了类似的结果,这表明粒子相互作用的内聚特性具有重要的依赖性。还考虑了其他无量纲数组,包括颗粒结合数和流动因子。为了研究表面力的影响,在计算颗粒结合数时使用了氧化铝和聚二甲基硅氧烷的 Hamaker 常数。随着 PDMS 的 Hamaker 常数减小,颗粒结合力也随之减小,这表明经过表面处理的粉末的表面力较小。
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