Synthesis of Carboxymethylcellulose–Acrylamide–Montmorillonite Composite Hydrogels for Wastewater Purification

Abstract

The three-dimensional network and ample pore structure of novel hydrogel materials enable outstanding adsorption performance for pollutants such as methylene blue (MB) and Cr6+ ions in wastewater. In order to develop an environmentally friendly hydrogel with high adsorption performance and low cost, a type of carboxymethyl cellulose (CMC) composite hydrogel was synthesised with montmorillonite (MMT) via chain radical polymerization, which gives it great potential for application in the field of wastewater purification. A series of hydrogel samples were characterised through SEM, FTIR and nitrogen porosimetry analysis, indicating the successful intercalation of MMT nanosheets into the hydrogel crosslinking network. The mass ratio of CMC to MMT, the amounts of adsorbent, the initial concentration of wastes, pH, and the adsorption temperature were investigated and optimised for hydrogel adsorption performance. When the initial concentration of MB is 60 mg/L, pH is 7, the dosage of MB is 0.5 g/L, and the adsorption temperature is 30 °C, the hydrogel sample the highest adsorption capability for MB removal, with an adsorption amount of 112.9 mg/g. When the initial concentration of Cr6+ is 10 mg/L with a pH of 7, the highest adsorption capacity of the hydrogel for Cr6+ removal is 1.35 mg/g. The fitting results of the isothermal models, the kinetic models, internal particle diffusion models and the thermodynamics of the experimental data of the adsorbate adsorption process show that the adsorption of MB by hydrogel is a spontaneous segmented process of multi-layer physical and chemical adsorption. Additionally, the adsorption of Cr6+ ions by hydrogel is a spontaneous segmented process of multi-layer physical adsorption.