Kükürtlenmiş Kayısıların Raf Ömrünü Uzatmada Kükürtün Etkisinin Kinetik İncelenmesi

Duygu Gürbüz, Yunus Önal, Tuğba Utku
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Abstract

In this study, sulphurized apricots with different sulfur values were obtained from the factory in Malatya province. These apricot samples were kept at market temperature values (4, 26 and 40°C) in the package offered for sale, and their sulfur dioxide values were determined daily. As a result of the experimental periods, reduction rate and other data were determined by calculating the sulfur dioxide in the sample. Also, loss rate and kinetics of sulfur dioxide were determined from its change over time at different temperatures. From the results obtained, important findings such as shelf life of sulphurous apricots at different temperatures in the package, deterioration and effect of the sulfur dioxide value on the shelf life were obtained. According to the analysis results of apricots containing different amounts of sulfur, when the moisture and SO2 loss in dried apricot samples during their stay on the shelf were examined in the kinetic study, it was determined that it was suitable for the first order kinetic model for 4°C and the second order kinetic model for 26 and 40°C. From the experimental results, quite low sulfur removal values were obtained for the samples offered for sale after 980 hours at 4°C and 525 hours at 26°C. Moisture and SO2 losses accelerated after approximately 740 hours at a temperature of 40°C. In the sample containing 3280 ppm sulfur dioxide during shelf storage at 4°C, there was an 11% loss of sulfur dioxide after 980 hours. A 46% sulfur dioxide loss was determined in the same samples after 740 hours at 40°C. It has been determined that sulfur dioxide loss is greater at higher temperatures. When the storage conditions of the samples were examined in terms of humidity, it was observed that apricots lost their moisture in the range of 52-85% after 29 days at temperatures of 4 and 40 °C. Based on the fact that the water activity of the packaged sulfurized dried apricots offered for sale is 25%, in this study, an average shelf life of approximately 25 days was determined according to this value.
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硫对延长硫化杏保质期影响的动力学研究
在这项研究中,从马拉蒂亚省的工厂获得了不同硫含量的硫化杏。这些杏子样品被保存在市场温度值(4、26 和 40°C)的包装中,每天测定其二氧化硫值。实验期间,通过计算样品中的二氧化硫,确定了还原率和其他数据。此外,还根据二氧化硫在不同温度下随时间的变化确定了其损失率和动力学。根据所获得的结果,得出了含硫杏在不同温度包装下的保质期、变质情况以及二氧化硫值对保质期的影响等重要结论。根据对含硫量不同的杏的分析结果,在动力学研究中考察杏干样品在货架上停留期间的水分和二氧化硫损失时,确定 4°C 时适合一阶动力学模型,26 和 40°C 时适合二阶动力学模型。从实验结果来看,在 4°C 下放置 980 小时和 26°C 下放置 525 小时后,出售的样品的脱硫值相当低。在温度为 40°C 时,大约 740 小时后,水分和二氧化硫的损失加速。在 4°C 的货架储藏期间,含 3280 ppm 二氧化硫的样品在 980 小时后二氧化硫损失了 11%。同样的样品在 40°C 下存放 740 小时后,二氧化硫的损失率为 46%。据测定,温度越高,二氧化硫的损失越大。从湿度的角度对样品的储藏条件进行检测时发现,在 4 和 40°C 温度下储藏 29 天后,杏子的水分损失在 52-85% 之间。在本研究中,出售的包装硫化杏干的水分活度为 25%,根据这一事实,确定杏干的平均保质期约为 25 天。
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