METHODS OF SYNTHESIS OF SILICATE-CONTAINING CLINKER DENTAL CEMENT

D. Mishin, V. Doroganov, E. Dolgova, Z. Tarallo, E. Evtushenko, E. Lukin
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Abstract

The article provides an overview of modern cements used in dentistry with an emphasis on silicate cements such as mineral trioxide aggregate (MTA). The basic requirements for dental cements are given, including their safety, adhesion to tooth tissues, resistance to various influences and thermal properties. The article analyzes in detail the composition and properties of industrial white Portland cement used in construction, in comparison with the characteristics of dental silicate cements. The general issues of the synthesis of high-base calcium silicates used in dentistry are considered from the standpoint of the chemical technology of Portland cement. The mineralogical composition and hydration processes of various cement components, their effect on tooth color and other properties are discussed. The methods of reducing the temperature and increasing the rate of formation of calcium silicates, common in the technology of dental cements and in the production of Portland cement, are indicated. It is assumed that it is possible to accelerate solid-phase synthesis in the range of 1250-1350 °C with a special method of introducing mineralizers proposed at the V.G. Shukhov BSTU for the synthesis of white Portland cement, provided it is adapted for dental formulations.
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含硅酸盐熟料牙科水泥的合成方法
文章概述了牙科中使用的现代水门汀,重点介绍了硅酸盐水门汀,如三氧化矿物骨料(MTA)。文章介绍了对牙科水门汀的基本要求,包括其安全性、与牙齿组织的粘附性、抗各种影响的能力以及热性能。 文章详细分析了建筑中使用的工业白硅酸盐水泥的成分和特性,并与牙科硅酸盐水泥的特性进行了比较。文章从波特兰水泥化学技术的角度出发,探讨了牙科用高碱硅酸钙合成的一般问题。讨论了各种水泥成分的矿物组成和水化过程,以及它们对牙齿颜色和其他特性的影响。 指出了在牙科水门汀技术和波特兰水门汀生产中常用的降低温度和提高硅酸钙形成率的方法。假定可以通过 V.G. Shukhov BSTU 提出的用于合成白色硅酸盐水泥的引入矿化剂的特殊方法在 1250-1350 °C范围内加速固相合成,前提是该方法适用于牙科配方。
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