Fabrication of Highly Efficient Fe3O4/SSIP/GO Composite Films for Removal of Methylene Blue Dye

M. S. Nas, M. H. Calimli, Özkan Demi̇rbaş
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Abstract

In this paper, we report the preparation of a new Fe3O4/SSIP/GO composite film for the purification of methylene blue dye from solution media. The preparation process of composite film was carried out to improve the interaction between the inner part of the sunflower stalk (SSIP) and surface matrix using magnetite/Graphene Oxide (Fe3O4/GO) minerals at weight ratios (0.2/4/0.2:w/w/w). The characterizations of as-developed Fe3O4/SSIP/GO composite film was successfully carried out by some advanced techniques such as FT-IR, SEM, and TGA analyses. Adsorption kinetic studies were evaluated in three different aspects as a pseudo-first-order model, pseudo-second-order model, and intraparticle diffusion-type model. Based on the R2 results, it was seen that the Pseudo-second order kinetic model (0.999) acted more harmoniously than the pseudo-first-order (0.960) and intra-particle diffusion technique models (0.974). In the light of these findings, it can be said that the prepared Fe3O4/SSIP/GO composite film used for removal of methylene blue dye can be considered as a promising material
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制备用于去除亚甲基蓝染料的高效 Fe3O4/SSIP/GO 复合薄膜
本文报告了一种新型 Fe3O4/SSIP/GO 复合薄膜的制备方法,用于从溶液介质中提纯亚甲基蓝染料。复合膜的制备过程是利用磁铁矿/氧化石墨烯(Fe3O4/GO)矿物以重量比(0.2/4/0.2:w/w/w)改善向日葵茎秆(SSIP)内部和表面基质之间的相互作用。通过一些先进的技术,如傅里叶变换红外光谱、扫描电镜和热重分析,成功地对开发的 Fe3O4/SSIP/GO 复合薄膜进行了表征。吸附动力学研究从三个不同方面进行了评估,分别是伪一阶模型、伪二阶模型和颗粒内扩散型模型。根据 R2 结果,伪二阶动力学模型(0.999)比伪一阶(0.960)和粒子内扩散技术模型(0.974)更协调。根据这些发现,可以认为制备的用于去除亚甲基蓝染料的 Fe3O4/SSIP/GO 复合薄膜是一种很有前景的材料。
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