Tuning Ag+ and Mn2+ doping in ZnS:Ag,Mn embedded polymers for flexible white light emitting films

Soft science Pub Date : 2024-01-04 DOI:10.20517/ss.2023.32
Lun Ma, E. Amador, George S. Belev, Chhabindra Gautam, Weidong Zhou, J. P. Liu, R. Sammynaiken, Wei Chen
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Abstract

Flexible Light Emitting Diodes are versatile lighting solutions that offer bendable and adaptable illumination possibilities. A soft, flexible white luminescent film (1 mm) shows promise for foldable electroluminescent devices and applications. This film was fabricated using ZnS:Ag and Mn. Under different excitation wavelengths, the phosphors emit blue light due to Ag+ luminescence centers and red light from the d-d transition of Mn2+. The blue emission is greatly suppressed at high Mn2+ doping levels, requiring reduced Ag+ doping in co-doped ZnS:Ag,Mn compared to solo-doped ZnS:Ag samples. By adjusting Ag+ and Mn2+ concentrations, the ZnS:Ag(1%),Mn(0.2%) phosphors show a proper intensity ratio of blue and red emissions, making them a promising candidate for future white light applications.
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调节 ZnS:Ag、Mn 嵌入聚合物中的 Ag+ 和 Mn2+ 掺杂,制造柔性白光发光薄膜
柔性发光二极管是一种多功能照明解决方案,可提供可弯曲和适应性强的照明可能性。一种柔软、灵活的白色发光薄膜(1 毫米)显示了可折叠电致发光器件和应用的前景。这种薄膜是用 ZnS:Ag 和 Mn 制成的。在不同的激发波长下,荧光粉因 Ag+ 发光中心而发出蓝光,因 Mn2+ 的 d-d 转变而发出红光。与单独掺杂的 ZnS:Ag 样品相比,在高 Mn2+掺杂水平下,蓝色发射被大大抑制,这就要求减少共掺杂 ZnS:Ag,Mn 中的 Ag+掺杂。通过调整 Ag+ 和 Mn2+ 的浓度,ZnS:Ag(1%),Mn(0.2%) 荧光粉显示出适当的蓝光和红光发射强度比,使其成为未来白光应用的理想候选材料。
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