{"title":"Riboflavin-Based Photocatalysis for Aerobic Oxidative S–N Bond Formation of Thiols and Amines","authors":"Marina Oka, Aki Takeda, Hiroki Iida","doi":"10.1093/chemle/upad057","DOIUrl":null,"url":null,"abstract":"\n A novel organophotocatalytic process using riboflavin derivatives, which allows for aerobic oxidative multistep S–S, S–N, and S–O bond formations of thiols and amines, is presented herein. The reaction proceeded under mild metal-free conditions using air (1 atm) as an environment-friendly oxidant, yielding sulfinamides and sulfonamides.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":"110 8","pages":""},"PeriodicalIF":1.4000,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upad057","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A novel organophotocatalytic process using riboflavin derivatives, which allows for aerobic oxidative multistep S–S, S–N, and S–O bond formations of thiols and amines, is presented herein. The reaction proceeded under mild metal-free conditions using air (1 atm) as an environment-friendly oxidant, yielding sulfinamides and sulfonamides.
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