Enhanced ammonia combustion by partial pre-cracking strategy in a gas turbine model combustor: Flame macrostructures, lean blowout characteristics and exhaust emissions

Abstract

Cofiring with hydrogen presents a reasonable approach to achieve enhanced ammonia (NH₃) combustion without introducing an extra carbon footprint. A promising strategy for NH₃/H₂ cofiring in gas turbines involves on-site partial pre-cracking of NH₃ and burns of NH₃/H₂/N₂ mixtures, eliminating additional hydrogen transportation and storage. This work investigates the effects of the pre-cracking ratio (γ) on flame macrostructures, lean blowout characteristics and exhaust emissions of the partially pre-cracked NH₃ flames in a single-swirl gas turbine model combustor. Flow and flame macrostructures were captured using particle image velocimetry (PIV) and OH planar laser-induced fluorescence (OH-PLIF) measurements. Lean blowout limits (ϕ_LBO) were assessed under varying γ, and emissions at the burner outlet were measured using a Fourier transform infrared spectroscopic (FTIR) gas analyzer. Results show that as γ increases, the flame exhibits a shortened height, strengthened OH fluorescence, amplified core jet velocities and significantly reduced ϕ_LBO, indicating an effective enhancement of NH₃ combustion by partial pre-cracking strategy. Nevertheless, NO and NO₂ emissions exhibit a substantial increase with larger γ. Opposite trends of NO and NH₃ emissions versus equivalence ratio (ϕ) suggest a trade-off between NO and NH₃ emissions, with relatively low NO/NH₃ window appearing under slightly-rich (ϕ = 1.0–1.1) conditions. Low NO emissions are also noted under ultra-lean conditions (ϕ = 0.4–0.5) with the penalty of high NH₃ and N₂O emissions, making it an unacceptable trade-off. Furthermore, the effect of N₂ separation from the partially pre-cracked NH₃ mixtures was evaluated at γ = 0.4. The results show deteriorating effects on NOx emissions, resulting in 13 % and 21 % increases in peak NO and NO₂ emissions, respectively, which implies more feasibility to burn the partially pre-cracked NH₃ in a direct manner rather than N₂ separation.