S. Shyam Kumar, Arun Kumar Panda, R. Mythili, Rajesh Ganesan
{"title":"Vapour pressure measurements on Nd–Te system","authors":"S. Shyam Kumar, Arun Kumar Panda, R. Mythili, Rajesh Ganesan","doi":"10.1007/s00706-023-03153-5","DOIUrl":null,"url":null,"abstract":"<p>Equilibrium vapour pressure measurements were carried out over the neodymium–tellurium samples using the non-isothermal isopiestic method. The samples were equilibrated in the temperature range from 821 to 1100 K. Using vapour pressure data obtained for the composition range ~ 64.0–74.5 at% Te, the thermodynamic activities of Te were determined. Non-stoichiometry in the NdTe<sub>2</sub> phase has been precisely determined under experimental conditions reported.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\n","PeriodicalId":19011,"journal":{"name":"Monatshefte für Chemie / Chemical Monthly","volume":"7 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Monatshefte für Chemie / Chemical Monthly","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1007/s00706-023-03153-5","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Equilibrium vapour pressure measurements were carried out over the neodymium–tellurium samples using the non-isothermal isopiestic method. The samples were equilibrated in the temperature range from 821 to 1100 K. Using vapour pressure data obtained for the composition range ~ 64.0–74.5 at% Te, the thermodynamic activities of Te were determined. Non-stoichiometry in the NdTe2 phase has been precisely determined under experimental conditions reported.