Synthesis and structure refinement of the zinc hydroxide boracite: Zn3B7O13(OH)

Raimund Ziegler, Sabrina Jungmann, H. Huppertz
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Abstract

Abstract The new zinc borate Zn3B7O13(OH) crystallizes trigonally in the space group R3c (no. 161) with the lattice parameters a = 849.76(3), c = 2099.8(2) pm, V = 1.3131(2) nm3, and six formula units per unit cell (Z = 6). It was synthesized at high-pressure/high-temperature conditions in a multianvil device. Single-crystal and powder X-ray diffraction experiments were conducted.
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氢氧化硼酸锌的合成与结构改进:Zn3B7O13(OH)
摘要 新型硼酸锌 Zn3B7O13(OH)在空间群 R3c(编号 161)中呈三棱结晶,其晶格参数为 a = 849.76(3),c = 2099.8(2) pm,V = 1.3131(2) nm3,每个单元格有六个公式单位(Z = 6)。它是在高压/高温条件下,在多管装置中合成的。进行了单晶和粉末 X 射线衍射实验。
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