An efficient and thermally stable source with Cr3+ near-infrared luminescence for non-destructive testing applications

Abstract

The quest for efficient and heat-resistant near-infrared (NIR) phosphors to create advanced smart NIR lighting sources continues to pose a significant challenge. This study introduces a new fluoride phosphor, Cr³⁺-doped Cs₂NaScF₆, wherein the Cs₂NaScF₆ host provides a weak crystal field suitable for Cr³⁺ doping. This arrangement allows the production of a broad NIR emission peaking at 797 nm, coupled with a notable internal quantum efficiency of 90.8 % when excited by 446 nm blue light. Meanwhile, due to the relatively mild electron-phonon coupling effect and a high activation energy within this phosphor, the overall NIR emission intensity at 150 °C sustains 81.8 % of its level at room temperature. This highlights exceptional thermal stability in photoluminescence performance. Combining the Cs₂NaScF₆:Cr³⁺ phosphor with a commercially available blue InGaN chip to construct a NIR light-emitting diode (LED) device, which exhibits efficient and stable NIR emission, making it suitable for non-destructive testing applications. These findings affirm that the Cs₂NaScF₆:Cr³⁺ phosphor can function as a promising candidate to fabricate high-performance device for NIR spectroscopy application.