Study on Methane Displacement Law of Coal with Different Metamorphic Degrees by N2 Injection

IF 0.8 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY Solid Fuel Chemistry Pub Date : 2024-01-15 DOI:10.3103/S0361521923070029
C. Ding, Z. Li
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Abstract

To reveal the mechanism of gas displacement in coal seam by N2, the desorption behavior of CH4 after N2 injection was studied by using giant canonical ensemble Monte Carlo (GCMC) and molecular dynamics (MD) methods. Through the adsorption and replacement of CH4 by N2 on three kinds of coal samples, the influence of different metamorphic coals on the replacement of CH4 by N2 was analyzed from the replacement amount and injection ratio. The results show that the average relative concentration of CH4 in vacuum layer increases after N2 implantation. The more N2 injection pressure, the more gas desorption. It can be seen from the two indexes of replacement amount and replacement ratio that CH4 replacement amount is positively correlated with coal metamorphic degree, while N2 injection ratio is negatively correlated with coal metamorphic degree. In the same coal, CH4 replacement amount is positively correlated with pressure, while N2 injection ratio is negatively correlated with pressure.

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注入 N2 对不同变质程度煤的甲烷置换规律研究
摘要 为揭示N2置换煤层瓦斯的机理,采用巨型集合蒙特卡洛(GCMC)和分子动力学(MD)方法研究了注入N2后CH4的解吸行为。通过三种煤样对 N2 对 CH4 的吸附和置换,从置换量和注入比分析了不同变质煤对 N2 置换 CH4 的影响。结果表明,N2 植入后,真空层中 CH4 的平均相对浓度增加。N2 注入压力越大,气体解吸量越大。从置换量和置换率两个指标可以看出,CH4 置换量与煤的变质程度呈正相关,而 N2 注入率与煤的变质程度呈负相关。在同一煤种中,CH4 置换量与压力呈正相关,而 N2 喷射比与压力呈负相关。
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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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