The Role of Kinetic Conditions on the Formation of a Perovskite Absorber in Increasing the Conversion Coefficients of Solar Cells

IF 1.204 Q3 Energy Applied Solar Energy Pub Date : 2024-01-16 DOI:10.3103/S0003701X22601600
A. O. Oblakulov, N. R. Ashurov, D. A. Toshmamatov, Z. N. Julliev, N. Sh. Ashurov, V. Yu. Sokolov, S. E. Maksimov, R. Yu. Rakhimov
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Abstract

The paper presents ways to improve the morphology and efficiency of perovskite solar cells synthesized from lead acetate trihydrate and methylammonium iodide. It was found that the quality of nanoscale films of the perovskite absorber depends on the time of precursor solution spinning and conditioning before annealing. The optimal combination of these times made it possible to increase the conversion coefficient and short-circuit current of perovskite solar cells to 10.97% and 18.7 mA/cm2, respectively. The results can be used to optimize the optoelectronic characteristics of perovskite depending on a number of kinetic parameters, such as the rotation speed, the acceleration time (acceleration) of the spin-coater, the temperature, and duration of annealing during the formation of solar cells.

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动力学条件对形成过氧化物吸收体以提高太阳能电池转换系数的作用
摘要 本文介绍了改善由三水醋酸铅和碘化甲铵合成的过氧化物太阳能电池的形态和效率的方法。研究发现,过氧化物吸收体纳米级薄膜的质量取决于前驱体溶液旋转和退火前调节的时间。这些时间的最佳组合使包晶石太阳能电池的转换系数和短路电流分别提高到 10.97% 和 18.7 mA/cm2。研究结果可用于优化包晶石的光电特性,具体取决于一些动力学参数,如太阳能电池形成过程中的旋转速度、旋涂器的加速时间(加速度)、温度和退火持续时间。
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来源期刊
Applied Solar Energy
Applied Solar Energy Energy-Renewable Energy, Sustainability and the Environment
CiteScore
2.50
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期刊介绍: Applied Solar Energy  is an international peer reviewed journal covers various topics of research and development studies on solar energy conversion and use: photovoltaics, thermophotovoltaics, water heaters, passive solar heating systems, drying of agricultural production, water desalination, solar radiation condensers, operation of Big Solar Oven, combined use of solar energy and traditional energy sources, new semiconductors for solar cells and thermophotovoltaic system photocells, engines for autonomous solar stations.
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