Mercury in Frozen Quaternary Sediments of the Spitsbergen Archipelago

IF 0.9 4区 地球科学 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Izvestiya Atmospheric and Oceanic Physics Pub Date : 2024-01-16 DOI:10.1134/s0001433823080054
N. E. Demidov, A. V. Guzeva, A. L. Nikulina, S. Wetterich, L. Schirrmeister
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Abstract

The climate warming–related degradation of permafrost can lead to the entry of climatically and biologically active substances, including mercury, into the biosphere; this work focuses on the analysis of the total content of mercury and organic carbon in 15 cores drilled in frozen Quaternary deposits of the Arctic Archipelago of Spitsbergen. The mercury content was additionally analyzed in bedrock samples, because the studied Quaternary deposits are formed by the weathering of the bedrock of the area. The results show that mercury concentrations in 157 studied samples of frozen Quaternary deposits range from 21 to 94 ng/g, with an average value of 40 ng/g. The expected correlation of mercury content with organic carbon content is not revealed. There are no trends in the accumulation of mercury depending on the lithological facies, geomorphological position, the time of sedimentation, or the freezing conditions. The average content of mercury in bedrock is relatively low, with a mean value of 8 ng/g. This means that the main source of mercury in frozen Quaternary deposits is not bedrock, but the formation of organic matter complexes or sorption on clay particles. In terms of the ongoing discussion about mercury input from permafrost to ecosystems, the results obtained from boreholes can be considered preindustrial background values.

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斯匹次卑尔根群岛冰冻第四纪沉积物中的汞
摘要 与气候变暖有关的永久冻土层退化可能导致包括汞在内的气候和生物活性物质进入生物圈;本研究重点分析了在斯匹次卑尔根北极群岛冰冻的第四纪沉积物中钻取的 15 个岩心中汞和有机碳的总含量。此外,还对基岩样本中的汞含量进行了分析,因为所研究的第四纪沉积物是由该地区的基岩风化形成的。结果表明,在 157 个研究的第四纪冰冻沉积物样本中,汞的浓度介于 21 至 94 纳克/克之间,平均值为 40 纳克/克。没有发现汞含量与有机碳含量之间的预期相关性。汞的积累与岩相、地貌位置、沉积时间或冰冻条件无关。基岩中汞的平均含量相对较低,平均值为 8 纳克/克。这意味着第四纪冰冻沉积物中汞的主要来源不是基岩,而是有机物复合物的形成或粘土颗粒的吸附。就目前关于汞从永久冻土层进入生态系统的讨论而言,从钻孔中获得的结果可视为工业化前的本底值。
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来源期刊
CiteScore
1.40
自引率
28.60%
发文量
56
审稿时长
6-12 weeks
期刊介绍: Izvestiya, Atmospheric and Oceanic Physics is a journal that publishes original scientific research and review articles on vital issues in the physics of the Earth’s atmosphere and hydrosphere and climate theory. The journal presents results of recent studies of physical processes in the atmosphere and ocean that control climate, weather, and their changes. These studies have possible practical applications. The journal also gives room to the discussion of results obtained in theoretical and experimental studies in various fields of oceanic and atmospheric physics, such as the dynamics of gas and water media, interaction of the atmosphere with the ocean and land surfaces, turbulence theory, heat balance and radiation processes, remote sensing and optics of both media, natural and man-induced climate changes, and the state of the atmosphere and ocean. The journal publishes papers on research techniques used in both media, current scientific information on domestic and foreign events in the physics of the atmosphere and ocean.
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