Interface Bonding Properties and Mechanism of Steel Fiber and Hot Melt Adhesive via Interface Design Engineering

IF 3.7 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2024-01-18 DOI:10.1021/acs.langmuir.3c03416
Tiancan Zhang, Shengkai Liu*, Xiaole Zhang, Xiaoyuan Pei, Xianyan Wu*, Shigang Luo, Wen Xu and Zhiwei Xu*, 
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Abstract

Steel fiber textile, which is composed of steel fibers and glass fibers, has a support layer impregnated with hot melt adhesive (HMA). During long-term service, the bonding force between the steel fiber/HMA system interfaces is poor. In order to improve the bond strength and durability of the interface, this paper introduced sandblasting, acid-etching, and phosphating treatments on the surface of the steel fibers. Also, the effects of these three pretreatment methods on the bond strength of the steel fiber/HMA interface were investigated. The results indicate that the interfacial bond strength of composites made from steel fibers is improved via surface treatment. Under a hydrothermal and simulated concrete pore solution environment, the durability of the steel fiber/HMA interface after sandblasting and acid-etching pretreatment is not as good as that after phosphating pretreatment. The mechanical properties of the phosphating/HMA composite were maintained at 4.56 and 2.24 times compared to those of the untreated/HMA composite, respectively. This is because the pinning effect formed by the phosphating film on the surface of steel fibers at the interface of steel fiber/HMA can serve as a physical barrier against corrosion, preventing the invasion of chloride ions and water vapor and improving the durability of the interface.

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通过界面设计工程实现钢纤维与热熔胶的界面粘合性能和机理。
钢纤维织物由钢纤维和玻璃纤维组成,其支撑层浸渍有热熔胶(HMA)。在长期使用过程中,钢纤维/HMA 系统界面之间的粘结力较差。为了提高界面的粘结强度和耐久性,本文对钢纤维表面进行了喷砂、酸蚀和磷化处理。同时,研究了这三种预处理方法对钢纤维/HMA 界面粘结强度的影响。结果表明,通过表面处理可以提高钢纤维复合材料的界面粘结强度。在水热和模拟混凝土孔溶液环境下,喷砂和酸蚀预处理后的钢纤维/HMA 界面的耐久性不如磷化预处理后的好。磷化/HMA 复合材料的力学性能分别是未处理/HMA 复合材料的 4.56 倍和 2.24 倍。这是因为在钢纤维/HMA 的界面上,磷化膜在钢纤维表面形成的针刺效应可作为防腐蚀的物理屏障,阻止氯离子和水蒸气的侵入,提高界面的耐久性。
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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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