Upcycling of composite packaging waste to carbon nanotubes via chemical vapor deposition of pyrolysis gas

Ece Turan , Umut Savacı , Zerrin Günkaya , Aysun Özkan , Müfide Banar
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Abstract

Based on the necessity of evaluating composite packaging wastes from both environmental and economic perspectives, it aimed to obtain carbon nanotube (CNT) from the pyrolysis gas product of this material by the catalytic chemical vapor deposition method (CCVD) via an upcycling approach. In the first stage, composite packaging wastes were pyrolyzed. Secondly, the composition of the gas via gas chromatography was determined. In the third stage, CNT production studies were carried out by the CCVD method in a tubular reactor at four different temperatures between 600 and 900 °C with nickel catalyst. The effects of temperature and carbon source feeding ratio on the properties of the obtained CNTs were investigated. CNTs produced in this study were compared with a commercial product. As a result, high-quality multi-walled carbon nanotube of 20–30 nm diameter and in micrometer scale length comparable to commercial products were produced from the gaseous product at 800 °C under Ni-catalysis.

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通过热解气体的化学气相沉积将复合包装废弃物升级再造为碳纳米管
基于从环境和经济角度评估复合包装废弃物的必要性,本研究旨在通过催化化学气相沉积法(CCVD),从该材料的热解气体产物中获取碳纳米管(CNT)。在第一阶段,对复合包装废弃物进行热解。第二阶段,通过气相色谱法测定气体成分。第三阶段,在管式反应器中使用镍催化剂,在 600 至 900 °C 四种不同温度下采用 CCVD 法进行 CNT 生产研究。研究了温度和碳源进料比对所获 CNT 特性的影响。研究中生产的碳纳米管与商业产品进行了比较。结果表明,在镍催化条件下,于 800 ℃ 从气态产品中制备出了直径为 20-30 nm、长度为微米级的高质量多壁碳纳米管,与商业产品相当。
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来源期刊
Environmental Nanotechnology, Monitoring and Management
Environmental Nanotechnology, Monitoring and Management Environmental Science-Water Science and Technology
CiteScore
13.00
自引率
0.00%
发文量
132
审稿时长
48 days
期刊介绍: Environmental Nanotechnology, Monitoring and Management is a journal devoted to the publication of peer reviewed original research on environmental nanotechnologies, monitoring studies and management for water, soil , waste and human health samples. Critical review articles, short communications and scientific policy briefs are also welcome. The journal will include all environmental matrices except air. Nanomaterials were suggested as efficient cost-effective and environmental friendly alternative to existing treatment materials, from the standpoints of both resource conservation and environmental remediation. The journal aims to receive papers in the field of nanotechnology covering; Developments of new nanosorbents for: •Groundwater, drinking water and wastewater treatment •Remediation of contaminated sites •Assessment of novel nanotechnologies including sustainability and life cycle implications Monitoring and Management papers should cover the fields of: •Novel analytical methods applied to environmental and health samples •Fate and transport of pollutants in the environment •Case studies covering environmental monitoring and public health •Water and soil prevention and legislation •Industrial and hazardous waste- legislation, characterisation, management practices, minimization, treatment and disposal •Environmental management and remediation
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