Origin of the Dashuigou independent tellurium deposit at Qinghai–Xizang Plateau: constraints from the light stable isotopes C, O, and H

IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Acta Geochimica Pub Date : 2024-01-11 DOI:10.1007/s11631-023-00665-z
Jianzhao Yin, Yuhong Chao, Haoyu Yin, Hongyun Shi, Shoupu Xiang
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Abstract

By studying the light isotopic compositions of carbon, oxygen, and hydrogen, combined with previous research results on the ore-forming source of the deposit, the authors try to uncover its metallogenic origin. The δ18O and δ13C isotope signatures of dolomite samples vary between 10.2 and 13.0‰, and between −7.2 and −5.2‰, respectively, implying that the carbon derives from the upper mantle. δD and δ18O of quartz, biotite, and muscovite from different ore veins of the deposit vary between −82 and −59‰, and between 11.6 and 12.4‰, respectively, implying that the metallogenic solutions are mainly magmatic. According to the relevant research results of many isotope geologists, the fractionation degree of hydrogen isotopes increases as the depth to the Earth’s core increases, and the more differentiated the hydrogen isotopes are, the lower their values will be. In other words, mantle-derived solutions can have extremely low hydrogen isotope values. This means that the δD‰ value − 134 of the pyrrhotite sample numbered SD-34 in this article may indicate mantle-derived ore-forming fluid of the deposit. The formation of the Dashuigou tellurium deposit occurred between 91.71 and 80.19 Ma.

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青藏高原大水沟独立碲矿床的起源:来自轻稳定同位素C、O和H的制约因素
通过研究碳、氧和氢的轻同位素组成,并结合以往对矿床成矿来源的研究成果,作者试图揭示其冶金成因。白云岩样品的δ18O和δ13C同位素特征分别在10.2-13.0‰和-7.2--5.2‰之间变化,表明碳来源于上地幔;矿床不同矿脉的石英、黑云母和蕈云母的δD和δ18O分别在-82--59‰和11.6--12.4‰之间变化,表明成矿溶液主要是岩浆。根据许多同位素地质学家的相关研究成果,氢同位素的分馏程度随着地核深度的增加而增加,氢同位素分化程度越高,其数值越低。换句话说,地幔衍生溶液的氢同位素值可能极低。这意味着本文中编号为 SD-34 的黄铁矿样品的 δD‰ 值 - 134 可能表示该矿床的地幔成矿流体。大水沟碲矿床形成于91.71-80.19Ma之间。
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来源期刊
Acta Geochimica
Acta Geochimica GEOCHEMISTRY & GEOPHYSICS-
CiteScore
2.80
自引率
6.20%
发文量
1134
期刊介绍: Acta Geochimica serves as the international forum for essential research on geochemistry, the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth‘s crust, its oceans and the entire Solar System, as well as a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. The journal focuses on, but is not limited to the following aspects: • Cosmochemistry • Mantle Geochemistry • Ore-deposit Geochemistry • Organic Geochemistry • Environmental Geochemistry • Computational Geochemistry • Isotope Geochemistry • NanoGeochemistry All research articles published in this journal have undergone rigorous peer review. In addition to original research articles, Acta Geochimica publishes reviews and short communications, aiming to rapidly disseminate the research results of timely interest, and comprehensive reviews of emerging topics in all the areas of geochemistry.
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