{"title":"Modeling low saline carbonated water flooding including surface complexes","authors":"","doi":"10.1007/s10596-024-10274-1","DOIUrl":null,"url":null,"abstract":"<h3>Abstract</h3> <p>Carbonated water flooding (CWI) increases oil production due to favorable dissolution effects and viscosity reduction. Accurate modeling of CWI performance requires a simulator with the ability to capture the true physics of such process. In this study, compositional modeling coupled with surface complexation modeling (SCM) are done, allowing a unified study of the influence in oil recovery of reduction of salt concentration in water. The compositional model consists of the conservation equations of total carbon, hydrogen, oxygen, chloride and decane. The coefficients of such equations are obtained from the equilibrium partition of chemical species that are soluble both in oleic and the aqueous phases. SCM is done by using the PHREEQC program, which determines concentration of the master species. Estimation of the wettability as a function of the Total Bound Product (TBP) that takes into account the concentration of the complexes in the aqueous, oleic phases and in the rock walls is performed. We solve analytically and numerically these equations in <span> <span>\\(1-\\)</span> </span>D in order to elucidate the effects of the injection of low salinity carbonated water into a reservoir containing oil equilibrated with high salinity carbonated water.</p>","PeriodicalId":10662,"journal":{"name":"Computational Geosciences","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Computational Geosciences","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.1007/s10596-024-10274-1","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS","Score":null,"Total":0}
引用次数: 0
Abstract
Carbonated water flooding (CWI) increases oil production due to favorable dissolution effects and viscosity reduction. Accurate modeling of CWI performance requires a simulator with the ability to capture the true physics of such process. In this study, compositional modeling coupled with surface complexation modeling (SCM) are done, allowing a unified study of the influence in oil recovery of reduction of salt concentration in water. The compositional model consists of the conservation equations of total carbon, hydrogen, oxygen, chloride and decane. The coefficients of such equations are obtained from the equilibrium partition of chemical species that are soluble both in oleic and the aqueous phases. SCM is done by using the PHREEQC program, which determines concentration of the master species. Estimation of the wettability as a function of the Total Bound Product (TBP) that takes into account the concentration of the complexes in the aqueous, oleic phases and in the rock walls is performed. We solve analytically and numerically these equations in \(1-\)D in order to elucidate the effects of the injection of low salinity carbonated water into a reservoir containing oil equilibrated with high salinity carbonated water.
期刊介绍：
Computational Geosciences publishes high quality papers on mathematical modeling, simulation, numerical analysis, and other computational aspects of the geosciences. In particular the journal is focused on advanced numerical methods for the simulation of subsurface flow and transport, and associated aspects such as discretization, gridding, upscaling, optimization, data assimilation, uncertainty assessment, and high performance parallel and grid computing.
Papers treating similar topics but with applications to other fields in the geosciences, such as geomechanics, geophysics, oceanography, or meteorology, will also be considered.
The journal provides a platform for interaction and multidisciplinary collaboration among diverse scientific groups, from both academia and industry, which share an interest in developing mathematical models and efficient algorithms for solving them, such as mathematicians, engineers, chemists, physicists, and geoscientists.
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