Miscibility of light oil and flue gas under thermal action

IF 7 Q1 ENERGY & FUELS Petroleum Exploration and Development Pub Date : 2024-02-01 DOI:10.1016/S1876-3804(24)60013-3
Changfeng XI , Bojun WANG , Fang ZHAO , Daode HUA , Zongyao QI , Tong LIU , Zeqi ZHAO , Junshi TANG , You ZHOU , Hongzhuang WANG
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Abstract

The miscibility of flue gas and different types of light oils is investigated through slender-tube miscible displacement experiment at high temperature and high pressure. Under the conditions of high temperature and high pressure, the miscible displacement of flue gas and light oil is possible. At the same temperature, there is a linear relationship between oil displacement efficiency and pressure. At the same pressure, the oil displacement efficiency increases gently and then rapidly to more than 90% to achieve miscible displacement with the increase of temperature. The rapid increase of oil displacement efficiency is closely related to the process that the light components of oil transit in phase state due to distillation with the rise of temperature. Moreover, at the same pressure, the lighter the oil, the lower the minimum miscibility temperature between flue gas and oil, which allows easier miscibility and ultimately better performance of thermal miscible flooding by air injection. The miscibility between flue gas and light oil at high temperature and high pressure is more typically characterized by phase transition at high temperature in supercritical state, and it is different from the contact extraction miscibility of CO2 under conventional high pressure conditions.

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轻油和烟道气在热作用下的混溶性
在高温高压条件下,通过细长管混溶置换实验研究了烟道气与不同类型轻油的混溶性。在高温高压条件下,烟气和轻油可以发生混溶置换。在相同温度下,油置换效率与压力呈线性关系。在相同压力下,随着温度的升高,油的置换效率先是平缓上升,然后迅速上升到 90% 以上,实现混溶置换。油品置换效率的快速提高与油品中的轻组分随着温度的升高在相态上发生蒸馏转变的过程密切相关。此外,在相同压力下,油的重量越轻,烟气和油的最低混溶温度就越低,这样就更容易混溶,最终提高了喷气式热混浸的性能。烟气与轻质油在高温高压下的混溶更典型地表现为超临界状态下的高温相变,它不同于常规高压条件下二氧化碳的接触萃取混溶。
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CiteScore
11.50
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0.00%
发文量
473
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