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Carbon isotope fractionation and production patterns of adsorbed and free gas during deep coal-rock gas production 深部煤岩气生产过程中吸附气和游离气的碳同位素分馏及生产模式
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60644-6
Xianggang DUAN , Wenbiao LI , Zhiming HU , Jun WANG , Qun ZHAO , Yonghui XIA , Zhanrong MA , Yingying XU , Mingyan SUN
Taking deep coal-rock gas in the Yulin and Daning-Jixian areas of the Ordos Basin, NW China, as the research object, full-diameter coal rock samples with different cleat/fracture development degrees from the Carboniferous Benxi Formation were selected to conduct physical simulation and isotope monitoring experiments of the full-life-cycle depletion development of coal-rock gas. Based on the experimental results, a dual-medium carbon isotope fractionation (CIF) model coupling cleats/fractures and matrix pores was constructed, and an evaluation method for free gas production patterns was established to elucidate the carbon isotope fractionation mechanism and adsorbed/free gas production characteristics during deep coal-rock gas development. The results show that the deep coal-rock gas development process exhibits a three-stage carbon isotope fractionation pattern: “Stable (I) → Decrease (II) → Increase (III)”. A rapid decline in boundary pressure in stage Ⅲ leads to fluctuations in isotope value, characterized by a “rapid decrease followed by continued increase”, with free gas being produced first and long-term supply of adsorbed gas. The CIF model can effectively match measured gas pressure, cumulative gas production, and δ13C1 value of produced gas. During the first two stages of isotope fractionation, free gas dominated cumulative production. During the mid-late stages of slow depletion production, the staged pressure control development method can effectively increase the gas recovery. The production of adsorbed gas is primarily controlled by the rock’s adsorption capacity and the presence of secondary flow channels. Effectively enhancing the recovery of adsorbed gas during the late stage remains crucial for maintaining stable production and improving the ultimate recovery factor of deep coal-rock gas.
以鄂尔多斯盆地榆林和大宁-吉县地区深部煤岩气为研究对象,选取石炭系本溪组不同裂隙/裂隙发育程度的全径煤岩样品,进行了煤岩气全生命周期衰竭发育的物理模拟和同位素监测实验。以实验结果为基础,构建了理缝/裂缝与基质孔隙耦合的双介质碳同位素分馏(CIF)模型,建立了游离产气模式评价方法,阐明了深部煤岩天然气开发过程中碳同位素分馏机理和吸附/游离产气特征。结果表明:深部煤岩气发育过程呈现出“稳定(I)→减少(II)→增加(III)”的三阶段碳同位素分馏模式;Ⅲ阶段边界压力迅速下降,导致同位素值波动,表现为“先降后升”,先产生游离气,长期供应吸附气。CIF模型能有效拟合实测气压力、累积产气量和采出气δ13C1值。在同位素分馏的前两个阶段,游离气占累积产量的主导地位。在慢衰竭生产中后期,采用分段压控开发方法可有效提高采收率。吸附气的产生主要受岩石的吸附能力和二次流通道的存在控制。有效提高后期吸附气的采收率,是保持深部煤岩气稳定生产和提高最终采收率的关键。
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引用次数: 0
Features and controlling factors of source-to-sink system during the fault-depression transition in a marine rift basin: A case study of Paleogene Oligocene Lingshui Formation in Qiongdongnan Basin, China 海相断陷盆地断陷转换源汇体系特征及控制因素——以琼东南盆地古近系渐新统陵水组为例
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60638-0
Wu TANG , Xiaojun XIE , Yaning WANG , Lianqiao XIONG , Jinxin YU , Shiqi WANG , Zhen ZHAO
Guided by the analysis of source-to-sink system, this study investigates the Paleogene Oligocene Lingshui Formation in the Qiongdongnan Basin by comparing the geological characterizes in land and sea areas and integrating outcrop, core, drilling, logging and 3D seismic data, to systematically analyze the characteristics of the source, transport pathway, and sink during the deposition of Lingshui Formation, and reveal the patterns, controlling factors and petroleum geologic significance of the source-to-sink systems. The results are obtained in five aspects. First, during the fault-depression transition, the Qiongdongnan Basin received sediments from the provenances presenting as segments in east-west and zones in north-south, primarily with the Indosinian granites in the Shenhu Uplift in the east and the Yanshanian granites in the west. Overall, the sources are young in the southern and northern parts and old in the interior of the basin. Second, three types of sediment transport pathways are identified: paleo-valleys, fault troughs and trough-valley transitional zones. Third, based on differences in sediment supply modes, the unique source-to-sink systems during the fault-depression transition in marine rift basins are categorized into three types: exogenous, endogenous and composite. Fourth, the characteristics of these source-to-sink systems are primarily controlled by provenance, paleogeomorphology, and sea-level changes. Provenance lithology and scale dictated the composition and volume of sedimentary deposits. Paleogeomorphology influenced erosion intensity in the provenance and the development of paleodrainage systems, thereby affecting the distribution and types of sedimentary systems. Additionally, sea-level changes decided the extent of the provenance, but also regulated the sediment distribution patterns through oceanic processes such as waves and tides. Fifth, the exogenous source-to-sink systems may form large-scale reservoir bodies, the endogenous systems develop secondary pores due to presence of soluble minerals, and the composite systems demonstrate reservoir properties varying from area to area.
本研究以源汇体系分析为指导,以琼东南盆地古近系渐新统陵水组为研究对象,通过对比陆海区地质特征,结合露头、岩心、钻井、测井、三维地震等资料,系统分析陵水组沉积时期的源、运、汇特征,揭示其规律。源-汇系统的控制因素及石油地质意义本文从五个方面进行了研究。首先,在断陷过渡时期,琼东南盆地的物源区呈东西分段、南北带状分布,东部以神虎隆起的印支期花岗岩为主,西部以燕山期花岗岩为主。总体而言,盆地南部和北部的烃源岩较年轻,盆地内部的烃源岩较老。其次,确定了古谷、断槽和槽谷过渡带三种输沙路径;第三,基于沉积物供给方式的差异,将海相裂谷盆地断陷转换过程中独特的源汇系统划分为外源、内源和复合三种类型。源-汇系统的特征主要受物源、古地貌和海平面变化的控制。物源岩性和规模决定了沉积矿床的组成和体积。古地貌影响物源侵蚀强度和古水系发育,从而影响沉积体系的分布和类型。此外,海平面的变化决定了物源的范围,但也通过波浪和潮汐等海洋过程调节了沉积物的分布模式。外源-汇体系可能形成大规模储集体,内源体系由于可溶性矿物质的存在而形成次生孔隙,复合体系表现出不同地区的储层性质。
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引用次数: 0
Waterflooding strategies for Cretaceous carbonate reservoirs with high permeability zones in the Middle East 中东地区白垩系碳酸盐岩高渗透油藏注水开发策略
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60641-0
Yong LI, Fengfeng LI, Chao YANG, Jiaheng CHEN, Yihang CHEN, Lei SHAO, Haiyang SU, Liang SUN
Based on the waterflooding development in carbonate reservoirs in the Middle East, this study analyzes the geological characteristics and waterflooding behaviors/patterns of different types of high permeability zones (HPZs), and proposes rational waterflooding strategies and modes. Four types of HPZs, i.e. sedimentation-dominated, sedimentation-diagenesis coupling, biogenic and composite, are identified in the carbonate reservoirs in the Middle East. Based on their distribution patterns, flow mechanisms, and waterflooding behaviors/patterns, five waterflooding modes are established: (1) the mode with stepwise-infilled areal vertical well pattern, for composite HFZs in patchy distribution; (2) the mode with regular row vertical well pattern for Type I channel “network” HFZs (with dominant water flow pathways at the base), and the mode with irregular differentiated vertical well pattern for Type II channel “network” HFZs (where multi-stage superimposition leads to “layered flooding”), for sedimentation-diagenesis coupling HFZs; (3) the mode with row horizontal wells through bottom injection and top production, for biogenic HFZs characterized by thin, contiguous distribution and rapid advancing of injected water along a 工-shaped path; and (4) the mode with progressive waterflooding through edge water injection via vertical well and oil production via horizontal well, for sedimentation-dominated HFZs characterized by thick, contiguous distribution and flood first in upper anti-rhythmic reservoirs. Development practices demonstrate that the proposed waterlooding modes are efficient in the highly heterogeneous carbonate reservoirs in the Middle East, with balanced employment of reserves in the adjacent reservoirs and enhanced oil recovery.
基于中东地区碳酸盐岩油藏水驱开发实践,分析了不同类型高渗透层的地质特征和水驱行为模式,提出了合理的水驱策略和水驱模式。在中东地区的碳酸盐岩储层中,发现了沉积主导型、沉积-成岩耦合型、生物成因型和复合成因型四种类型的高压带。根据它们的分布规律、流动机理和水驱行为模式,建立了5种水驱模式:(1)块状分布的复合hfz为区域直井逐步充填模式;(2)ⅰ型通道“网络”型高通量区为规则排直井模式(以基底为主导水流通道),ⅱ型通道“网络”型高通量区为不规则分异直井模式(多段叠加形成“层状驱水”);(3)以单排水平井为主的下注上采模式,适用于注入水薄、分布连续、注入水沿“一字形”路径快速推进的生物源高射区;(4)针对上部抗韵律储层厚度大、分布连续、以沉积为主的高通量区,采用直井边注递进注水、水平井采油模式。开发实践表明,所提出的注水模式在中东地区高度非均质碳酸盐岩储层中是有效的,可以平衡利用相邻储层的储量,提高石油采收率。
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引用次数: 0
Mechanisms of hydrated ion bridges in the development of low and ultra-low permeability reservoirs 水合离子桥在低、特低渗透油藏开发中的作用机理
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60642-2
Xu JIN , Fenglu CUI , Yining WU , Xiaoqi WANG , Siwei MENG , Chenjun ZHANG , Xiaodan LIU , Jiaping TAO , Man SHEN , Fengchao WANG
This study focuses on the hydrated ion bridge (HIB) effect at the oil-rock interface in low- to ultra-low-permeability oil reservoirs. It systematically summarizes the research methodologies, formation mechanisms, interaction strength, and disruption mechanisms of HIB, and discusses the influencing mechanisms of HIB on the occurrence state and mobility of crude oil. On this basis, the key challenges inherent in the current HIB research are analyzed, and prospective directions for future development are proposed. Currently, research in this field primarily relies on experimental characterization techniques and molecular simulation methods. The microscopic interactions involved in HIB formation mainly include electrostatic interactions, hydrogen bonds and van der Waals forces. Notably, the hydrogen bonds between polar molecules in crude oil and hydrated ions serve as the primary sites for disrupting the HIB effect. The interaction strength of HIB is collectively modulated by ion type and concentration, reservoir solution environment, mineral type of reservoir rocks, and polar components in crude oil, which subsequently influence the occurrence state and mobility of crude oil. Systematic challenges persist in HIB-related research across three dimensions: research methodologies, scale integration and geological complexity. Specifically, the dynamic evolution mechanism of HIB remains inadequately elucidated; a discontinuity exists in the connection of spatiotemporal cross-scale modeling and prediction; and the reproducibility of actual geological environments in experimental settings is insufficient. Future research may pursue breakthroughs in the following three aspects: (1) developing in-situ dynamic experimental characterization techniques and machine learning-augmented simulation strategies; (2) establishing a framework for cross-scale model fusion and upscaling prediction; and (3) conducting in-depth studies on HIB under the coupled effects of complex mineral systems and multi-physical fields.
研究了低-特低渗透油藏中油岩界面的水合离子桥效应。系统总结了HIB的研究方法、形成机理、相互作用强度和破坏机理,探讨了HIB对原油赋存状态和流动性的影响机理。在此基础上,分析了当前HIB研究面临的主要挑战,并提出了未来发展的展望方向。目前,该领域的研究主要依靠实验表征技术和分子模拟方法。HIB形成过程中涉及的微观相互作用主要包括静电相互作用、氢键和范德华力。值得注意的是,原油中极性分子与水合离子之间的氢键是破坏HIB效应的主要位点。HIB的相互作用强度受离子类型和浓度、储层溶液环境、储层岩石矿物类型、原油极性组分等因素的共同调节,进而影响原油的赋存状态和流动性。hib相关研究的系统性挑战存在于三个方面:研究方法、规模整合和地质复杂性。具体而言,HIB的动态演化机制尚未得到充分阐明;时空跨尺度模拟与预测之间存在不连续;实验环境对实际地质环境的再现性不足。未来的研究可能在以下三个方面寻求突破:(1)开发原位动态实验表征技术和机器学习增强仿真策略;(2)建立跨尺度模型融合和上尺度预测框架;(3)深入研究复杂矿物系统与多物理场耦合作用下的HIB。
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引用次数: 0
Propagation characteristics of multiple clusters of fractures in fully coupled wellbore-perforation-fracture fracturing 井筒-射孔-裂缝全耦合压裂中多裂缝簇的扩展特征
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60647-1
Peng YANG , Yushi ZOU , Shicheng ZHANG , Jianmin LI , Xiaohuan ZHANG , Xinfang MA , Lifeng YANG
Based on the Low Frequency Distributed Acoustic Sensing (LF-DAS) fiber optic monitoring and downhole hawk-eye imaging, the fluid and sand distribution and perforation erosion of all clusters during hydraulic fracturing were evaluated, and then a fully coupled wellbore-perforation-fracture numerical model was established to simulate the whole process of sand-carrying fluid migration and analyze key influencing factors. The proppant and fracturing fluid exhibit divergent flow pathways during multi-staged, multi-cluster fracturing in horizontal wells, resulting in significant heterogeneity in the fluid-proppant distribution among clusters. Perforation erosion is prevalent, and perforation erosion and sand inflow ratio have phase bias. The trajectory of proppant transport is controlled by the combined effects of inertia of particle migration and gravity settlement. The inertial effect is dominant at the wellbore heel, where the fluid flow rate is high, hindering particles turning into perforations and causing uneven sand distribution among clusters. The gravity settlement is more pronounced toward the wellbore toe, where the fluid flow rate is low, leading to enhanced phase-bias of slurry distribution and perforation erosion. Increasing the pumping rate reduces the influence of gravity settlement, mitigating the phase bias of sand inflow and perforation erosion. However, the large pumping rate limits the sand inflow efficiency near the heel clusters, and more proppants accumulate towards the toe clusters. High-viscosity fluids improve particle suspension, achieving more uniform proppant placement within wellbore and fractures. Larger particle sizes exacerbate sand inflow differences among clusters and perforations, limiting the proppant placement range within fractures.
基于低频分布声传感(LF-DAS)光纤监测和井下鹰眼成像技术,对水力压裂过程中各簇的流体、砂分布和射孔侵蚀进行了评价,建立了全耦合井筒-射孔-裂缝数值模型,模拟了携砂流体运移全过程,分析了关键影响因素。在水平井多级、多簇压裂过程中,支撑剂和压裂液表现出不同的流动路径,导致流体-支撑剂在簇间分布的非均质性显著。射孔冲蚀现象普遍,射孔冲蚀与入砂比存在相位偏差。支撑剂的运移轨迹受颗粒运移惯性和重力沉降的共同作用控制。惯性效应在井眼跟部起主导作用,流体流速高,阻碍颗粒进入射孔,导致砂粒在簇间分布不均匀。在流体流速较低的井趾处,重力沉降更为明显,导致泥浆分布的相偏加剧和射孔侵蚀。提高泵送速率可以降低重力沉降的影响,减轻砂流的相位偏差和射孔侵蚀。然而,较大的泵送速率限制了砂体流入跟簇附近的效率,更多的支撑剂向趾簇积聚。高粘度流体改善颗粒悬浮,在井筒和裂缝中实现更均匀的支撑剂放置。较大的颗粒尺寸加剧了簇间和射孔间的入砂差异,限制了支撑剂在裂缝内的放置范围。
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引用次数: 0
A new type of unconventional natural gas resources: Overpressure-dissolved gas 一种新型非常规天然气资源:超压溶解气
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60648-3
Yuhong XIE
In overpressure reservoirs, natural gas often coexists in a three-phase mixed form of continuous free state, dispersed free state and water-saturated dissolved state. However, the latter two have not received sufficient attention. In response to this situation, based on detailed characterization of typical overpressure dissolved gas in the Yinggehai-Qiongdongnan basin and the experiment results of natural gas dissolution with high-temperature and overpressure, the concept of “overpressure-dissolved gas” was proposed and its basic features, formation conditions and resource potential were summarized. It refers to the natural gas present in the gas-water transitional zone and the saturated dissolved gas zone within the overpressure reservoirs. The formation of overpressure-dissolved gas requires two basic conditions: the pressure coefficient typically greater than 1.5, and a relatively high gas saturation in the reservoir (10%–35%). Overpressure-dissolved gas exists in the strata from shallow to deep with a multi-stage superimposed pattern; there are at least four combination types: overpressure- dissolved gas with multiple gas caps, overpressure-dissolved gas with single gas cap, gas-bearing water layer without gas cap, and dissolved gas-bearing water layer without gas cap. The basic geological elements required for the formation of overpressure-dissolved gas include the gas source, reservoir, cap rock, gas-water transitional zone and overpressure body. The conditions of gas source, reservoir and cap rock determine the scale of the overpressure-dissolved gas zone. High temperature, high pressure and low-permeability reservoirs control the solubility of natural gas and the thickness of the gas-water transitional zone. The physical properties of sandstone determine the combination types of overpressure-dissolved gas. Changes in pressure control the transformation of different existing states of overpressure-dissolved gas. The overpressure-dissolved gas in the Yinggehai-Qiongdongnan Basin has considerable huge resource potential. Once breakthrough is achieved in this area, it will usher in a new era of natural gas exploration in the overpressured basin.
在超压储层中,天然气常以连续游离态、分散游离态和水饱和溶解态三相混合形式共存。然而,后两者并没有得到足够的重视。针对这一情况,在详细描述莺歌海-琼东南盆地典型超压溶解气特征的基础上,结合天然气高温超压溶解实验结果,提出了“超压溶解气”的概念,总结了超压溶解气的基本特征、形成条件和资源潜力。它是指存在于超压储层内气水过渡带和饱和溶气带的天然气。超压溶气的形成需要两个基本条件:压力系数一般大于1.5,储层含气饱和度较高(10% ~ 35%)。超压溶气由浅至深呈多期叠加分布;超压溶气至少有4种组合类型:多气顶的超压溶气、单气顶的超压溶气、无气顶的含气水层、无气顶的含气水层。形成超压溶气所需的基本地质要素包括气源、储层、盖层、气水过渡带和超压体。气源条件、储层条件和盖层条件决定了超压溶气区的规模。高温、高压、低渗透储层控制着天然气的溶解度和气水过渡带厚度。砂岩的物性决定了超压溶气的组合类型。压力的变化控制着超压溶解气体不同存在状态的转变。莺歌海-琼东南盆地超压溶气具有相当巨大的资源潜力。一旦该地区取得突破,将迎来超压盆地天然气勘探的新时代。
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引用次数: 0
Microscopic mechanisms of intrasource micro-migration and enrichment of lacustrine shale oil: A case study of Chang73 submember of Triassic Yanchang Formation, Ordos Basin, NW China 湖相页岩油源内微运移富集微观机制——以鄂尔多斯盆地延长组长73亚段为例
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60639-2
Yingzhu WANG , Yuting HOU , Jijin YANG
To clarify the mechanism of differential enrichment of intrasource shale oil, taking the third of seventh member of the Triassic Yanchang Formation (Chang73 submember for short) in the Ordos Basin, NW China as an example, we integrated high-resolution scanning electron microscopy (SEM), optical microscopy, laser Raman spectroscopy, rock pyrolysis, and organic solvent extraction experiments to identify solid bitumen of varying origins, obtain direct evidence of intrasource micro-migration of shale oil, and establish the coupling between the shale nano/micro-fabric and the oil generation, migration and accumulation. The Chang73 shale with rich alginite in laminae has the highest hydrocarbon generation potential but a low thermal transformation ratio. Frequent alternations of micron-scale argillaceous-felsic laminae enhance the hydrocarbon expulsion efficiency, yielding consistent aromaticity between in-situ and migrated solid bitumen. Mudstone laminae rich in terrestrial organic matter (OM) and clay minerals exhibit lower hydrocarbon generation threshold but stronger hydrocarbon retention capacity, with a certain amount of light oil/bitumen preserved to differentiate the chemical structure of in-situ versus migrated bitumen. Tuffaceous and sandy laminae contain abundant felsic minerals and migrated bitumen. Tuffaceous laminae develop high-angle microfractures under shale overpressure, facilitating oil charging into rigid mineral intergranular pores of sandy laminae. Fractionation during micro-migration progressively decreases the aromatization of solid bitumen from shale, through tuffaceous and mudstone, to sandy laminae, while increasing light hydrocarbon components and enhancing OM-hosted pore development. The intrasource micro-migration and enrichment of the Chang73 shale oil result from synergistic organic-inorganic diagenesis, with crude oil component fractionation being a key mechanism for forming sweet spots in laminated shale oil reservoirs.
为明确源内页岩油差异富集机理,以鄂尔多斯盆地三叠系延长组3—7段(简称长73亚段)为例,综合运用高分辨率扫描电镜(SEM)、光学显微镜、激光拉曼光谱、岩石热解、有机溶剂萃取等实验手段,对不同成因的固体沥青进行了识别。获得页岩油源内微运移的直接证据,建立页岩纳米/微组构与生油、运移、聚集的耦合关系。长73页岩生烃潜力最大,但热转化率较低。微米级泥质-长英质纹层的频繁交替提高了排烃效率,使原位和迁移固体沥青具有一致的芳香性。富含陆相有机质和粘土矿物的泥岩纹层生烃阈值较低,持烃能力较强,并保留了一定数量的轻质油/沥青,以区分原位沥青和运移沥青的化学结构。凝灰岩和砂质纹层中含有丰富的长英质矿物和迁移沥青。凝灰质纹层在页岩超压作用下发育高角度微裂缝,有利于原油充注到砂质纹层的刚性矿物粒间孔隙中。微运移过程中的分馏作用逐渐降低了页岩、凝灰岩、泥岩、砂质纹层中固体沥青的芳构化程度,同时增加了轻烃组分,增强了有机质孔隙发育。长73页岩油的源内微运移富集是有机-无机协同成岩作用的结果,原油组分分馏是层状页岩油储集层甜点形成的关键机制。
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引用次数: 0
A saturation model of lacustrine shale oil considering the influence of organic matter: A case study of the first member of the Cretaceous Qingshankou Formation of Changling Sag in southern Songliao Basin, NE China 考虑有机质影响的湖相页岩油饱和模式——以松辽盆地南部长岭凹陷白垩系青山口组一段为例
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60636-7
Dianshi XIAO , Zhuo LI , Min WANG , Wei DANG , Xiaoquan XIE , Baifeng HAN
Taking the shale oil of the first member of the Cretaceous Qingshankou Formation of Changling Sag in southern Songliao Basin as an example, this paper establishes a saturation model of lacustrine shale oil considering the influence of organic matter on clay-bound water conductivity. Based on the fluid characterization results of sealed samples and two-dimensional nuclear magnetic resonance, the differential influence of organic matter on clay-bound water conductivity was quantitatively revealed, and the conductivity mechanism and rock-electrical relationships of lacustrine shale were systematically analyzed. The results show that there are two conductive networks for lacustrine shales, i.e. the matrix free water and the clay-bound water. The bound water cementation index msh was introduced to reflect the impact of organic matter on clay-bound water conductivity, and it is positively correlated with the effective porosity. When there is sufficient rigid framework support and well-developed pores, organic matter is more likely to fill or adsorb onto clay interlayers. This reduces the ion exchange capacity of the electrical double layer, leading to an increase in msh and a decrease in the conductivity of clay-bound water. The overall conductivity of shale is controlled by the clay-bound water conductivity, and the relative contributions of the mentioned two conductive networks to formation conductivity are affected by the effective porosity and msh. The larger the effective porosity and msh, the more the contribution of the matrix free water to formation conductivity. According to the experimental results, the proposed saturation model yields a significantly higher interpretation accuracy in oil saturation than the Archie model and the Total-shale model.
以松辽盆地南部长岭凹陷白垩系青山口组一段页岩油为例,建立了考虑有机质对泥水导电性影响的湖相页岩油饱和度模型。基于密封样品流体表征结果和二维核磁共振,定量揭示了有机质对粘土结合水电导率的差异性影响,系统分析了湖相页岩的电导率机理和岩电关系。结果表明,湖相页岩存在基质自由水和粘土结合水两种导电网络。引入黏结水胶结指数msh反映有机质对黏结水导电性的影响,其与有效孔隙度呈正相关。当有足够的刚性骨架支撑和发育良好的孔隙时,有机质更容易填充或吸附到粘土夹层上。这降低了双电层的离子交换能力,导致msh的增加和粘土结合水电导率的降低。页岩整体导电性受粘土结合水导电性控制,两种导电性网络对地层导电性的相对贡献受有效孔隙度和msh的影响。有效孔隙度和msh越大,无基质水对地层导电性的贡献越大。实验结果表明,该模型对含油饱和度的解释精度明显高于Archie模型和Total-shale模型。
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引用次数: 0
Research progress and key research directions of shale oil in lacustrine rift basins 湖相裂谷盆地页岩油研究进展及重点研究方向
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60629-X
Xusheng GUO , Baojian SHEN , Maowen LI , Huimin LIU , Zhiming LI , Shicheng ZHANG , Yong YANG , Jingyi GUO , Yali LIU , Peng LI , Xiaoxiao MA , Mengyun ZHAO , Pei LI , Chenjia ZHANG , Zihan WANG
Lacustrine rift basins in China are characterized by pronounced structural segmentation, strong sedimentary heterogeneity, extensive fault-fracture development, and significant variability in thermal maturity and mobility of shale oil. This study reviews the current status of exploration and development of shale oil in such basins and examines theoretical frameworks such as “binary enrichment” and source–reservoir configuration, with a focus on five key subjects: (1) sedimentation-diagenesis coupling mechanisms of fine-grained shale reservoir formation; (2) dynamic diagenetic evolution and hydrocarbon occurrence mechanisms of organic-rich shale; (3) dominant controls and evaluation methods for shale oil enrichment; (4) fracturing mechanisms of organic-rich shale and simulation of artificial fracture networks; and (5) flow mechanisms and effective development strategies for shale oil. Integrated analysis suggests that two major scientific challenges must be addressed: the coupled evolution of fine-grained sedimentation, differential diagenesis, and hydrocarbon generation under tectonic influence and its control on shale oil occurrence and enrichment; and multi-scale, multiphase flow mechanisms and three-dimensional development strategies for lacustrine shale oil in complex fault blocks. In response to current exploration and development bottlenecks, future research will be conducted primarily to: (1) deeply understand organic-inorganic interactions and reservoir formation mechanisms in organic-rich shales, and clarify the influence of high-frequency sequence evolution and diagenetic fluids on reservoir space; (2) elucidate the dynamic processes of hydrocarbon generation, expulsion, and retention across different lithofacies, and quantify their relationship with thermal maturity, including the conditions for the formation of self-sealing systems; (3) develop a geologically adaptive, data- and intelligence-driven shale oil classification and grading evaluation system of shale oil; (4) reveal artificial fracture propagation pattern and optimize physical field coupled fracturing technologies for complex lithofacies assemblages; and (5) overcome challenges in multi-scale geological modeling and multiphase flow characterization, and establish advanced numerical simulation methodologies.
中国湖相裂谷盆地具有构造分段性强、沉积非均质性强、断裂发育广泛、页岩油热成熟度和运移能力变异性显著的特点。本文综述了此类盆地页岩油勘探开发现状,探讨了“二元富集”、源储配置等理论框架,重点研究了5个关键问题:(1)细粒页岩储层形成的沉积—成岩耦合机制;(2)富有机质页岩动态成岩演化与油气赋存机制;(3)页岩油富集主控因素及评价方法;(4)富有机质页岩压裂机理及人工裂缝网络模拟;(5)页岩油渗流机理与有效开发策略。综合分析认为,必须解决两大科学挑战:构造影响下的细粒沉积、差异成岩和生烃耦合演化及其对页岩油赋存富集的控制;复杂断块湖相页岩油多尺度多相流动机理及三维开发策略。针对当前的勘探开发瓶颈,今后的研究重点将是:(1)深入了解富有机质页岩中有机-无机相互作用和成藏机制,明确高频层序演化和成岩流体对储层空间的影响;(2)阐明不同岩相的生、排、藏烃动力学过程,量化其与热成熟度的关系,包括形成自封闭体系的条件;(3)建立地质适应性强、数据和智能驱动的页岩油分类分级评价体系;(4)揭示复杂岩相组合人工裂缝扩展模式,优化物性场耦合压裂技术;(5)克服多尺度地质建模和多相流表征的挑战,建立先进的数值模拟方法。
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引用次数: 0
Orderly distribution and differential enrichment of conventional and unconventional hydrocarbons in the Cretaceous Qingshankou Formation, northern Songliao Basin, NE China 松辽盆地北部白垩系青山口组常规与非常规油气有序分布及差异富集
IF 8 Q1 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/S1876-3804(25)60631-8
Xuefeng BAI , Junhui LI , Qiang ZHENG , Fangju CHEN
Based on the petroleum exploration in the Cretaceous Qingshankou Formation, northern Songliao Basin, NE China, integrated with seismic, drilling and logging data, this study investigates the characteristics and genetic mechanisms of orderly distribution and the differential enrichment patterns of conventional and unconventional hydrocarbons in the formation. Key findings involve five aspects. First, the conventional and unconventional hydrocarbons coexist orderly. Laterally, conventional oil, tight oil, and shale oil form a pattern of orderly accumulation from basin margins to the center. Vertically, shale oil, tight oil, and conventional oil develop progressively upward. Second, the coupled tectonic-sedimentary processes govern sedimentary facies differentiation and diagenesis, influencing reservoir physical properties and lithology, thereby controlling the orderly distribution of conventional and unconventional hydrocarbons in space. Third, the coupling of source rock hydrocarbon generation evolution, fault sealing capacity, and reservoir densification determines the orderly coexistence pattern of conventional and unconventional hydrocarbons. Fourth, sequential variations in reservoir physical properties generate distinct dynamic fields that regulate hydrocarbon orderly accumulation. Fifth, enrichment controls are different depending on hydrocarbon types: buoyancy-driven, fault-transport, sandbody-connected, and trap-concentrated, for above-source conventional oil; overpressure-driven, fault-transport, multi-stacked sandbodies, and quasi-continuous distribution for near-source tight oil and gas; self-sourced reservoirs, retention through self-sealing, in-situ accumulation or micro-migration driven by hydrocarbon-generation overpressure for inner-source shale oil. From exploration practices, these findings will effectively guide the integrated deployment and three-dimensional exploration of conventional and unconventional hydrocarbon resources in the Qingshankou Formation, northern Songliao Basin.
以松辽盆地北部白垩系青山口组油气勘探为基础,结合地震、钻井、测井等资料,探讨了该组常规与非常规油气有序分布特征、成因机制及差异富集模式。主要发现包括五个方面。首先,常规和非常规碳氢化合物有序共存。横向上,常规油、致密油、页岩油形成了由盆地边缘向中心有序聚集的格局。纵向上,页岩油、致密油、常规油依次向上开发。其次,构造-沉积耦合作用控制沉积相分异和成岩作用,影响储层物性和岩性,从而控制常规和非常规油气在空间上的有序分布。第四,储层物性的序列变化形成了不同的动力场,控制着油气有序聚集。第五,不同油气类型的富集控制也不同:对于源上常规油,浮力驱动型、断层输运型、砂体连通型和圈闭集中型;超压驱动、断层输运、多层砂体、近源致密油气准连续分布;自源储层、自封闭储层、生烃超压驱动的原位聚集或微运移。从勘探实践看,这些发现将有效指导松辽盆地北部青山口组常规与非常规油气资源的综合部署和三维勘探。
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引用次数: 0
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Petroleum Exploration and Development
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