Desirable candidates for high-performance lead-free organic–inorganic halide perovskite solar cells

IF 3.6 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials for Renewable and Sustainable Energy Pub Date : 2024-02-16 DOI:10.1007/s40243-024-00255-w
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Abstract

Perovskite solar cells (PSCs) are currently demonstrating tremendous potential in terms of straightforward processing, a plentiful supply of materials, and easy architectural integration, as well as high power conversion efficiency (PCE). However, the elemental composition of the widely utilized organic–inorganic halide perovskites (OIHPs) contains the hazardous lead (Pb). The presence of Pb in the PSCs is problematic because of its toxicity which may slow down or even impede the pace of commercialization. As a backup option, the scientific community has been looking for non-toxic/less-toxic elements that can replace Pb in OIHPs. Despite not yet matching the impressive results of Pb-containing OIHPs, the community is paying close attention to Pb-free materials and has seen some encouraging findings. This review evaluates the Pb-replacement with suitable elements and scrutinizes the desirable optoelectronic features of such elements in OIHPs. The fundamental features of Pb-free OIHPs together with their photovoltaic performance in the PSCs are evaluated in details. Finally, we sum up the current challenges and potential opportunities for the Pb-free OIHPs and their devices.

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高性能无铅有机无机卤化物包晶太阳能电池的理想候选材料
摘要 目前,过氧化物太阳能电池(PSCs)具有加工简单、材料供应充足、易于建筑集成以及功率转换效率高(PCE)等巨大潜力。然而,广泛使用的有机无机卤化物包晶石(OIHPs)的元素组成中含有有害物质铅(Pb)。由于铅的毒性,PSCs 中含有铅是一个问题,这可能会减缓甚至阻碍商业化的步伐。作为后备方案,科学界一直在寻找可以替代 OIHP 中铅的无毒/低毒元素。尽管还无法与含铅 OIHPs 取得的令人瞩目的成果相媲美,但科学界正在密切关注无铅材料,并取得了一些令人鼓舞的研究成果。本综述评估了用合适元素替代铅的情况,并仔细研究了这些元素在 OIHP 中的理想光电特性。此外,还详细评估了无铅 OIHP 的基本特征及其在 PSC 中的光电性能。最后,我们总结了无铅 OIHP 及其器件当前面临的挑战和潜在机遇。
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来源期刊
Materials for Renewable and Sustainable Energy
Materials for Renewable and Sustainable Energy MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
7.90
自引率
2.20%
发文量
8
审稿时长
13 weeks
期刊介绍: Energy is the single most valuable resource for human activity and the basis for all human progress. Materials play a key role in enabling technologies that can offer promising solutions to achieve renewable and sustainable energy pathways for the future. Materials for Renewable and Sustainable Energy has been established to be the world''s foremost interdisciplinary forum for publication of research on all aspects of the study of materials for the deployment of renewable and sustainable energy technologies. The journal covers experimental and theoretical aspects of materials and prototype devices for sustainable energy conversion, storage, and saving, together with materials needed for renewable fuel production. It publishes reviews, original research articles, rapid communications, and perspectives. All manuscripts are peer-reviewed for scientific quality. Topics include: 1. MATERIALS for renewable energy storage and conversion: Batteries, Supercapacitors, Fuel cells, Hydrogen storage, and Photovoltaics and solar cells. 2. MATERIALS for renewable and sustainable fuel production: Hydrogen production and fuel generation from renewables (catalysis), Solar-driven reactions to hydrogen and fuels from renewables (photocatalysis), Biofuels, and Carbon dioxide sequestration and conversion. 3. MATERIALS for energy saving: Thermoelectrics, Novel illumination sources for efficient lighting, and Energy saving in buildings. 4. MATERIALS modeling and theoretical aspects. 5. Advanced characterization techniques of MATERIALS Materials for Renewable and Sustainable Energy is committed to upholding the integrity of the scientific record. As a member of the Committee on Publication Ethics (COPE) the journal will follow the COPE guidelines on how to deal with potential acts of misconduct. Authors should refrain from misrepresenting research results which could damage the trust in the journal and ultimately the entire scientific endeavor. Maintaining integrity of the research and its presentation can be achieved by following the rules of good scientific practice as detailed here: https://www.springer.com/us/editorial-policies
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