Effect of titanium diboride on the rheological characteristics of silica-based polyethylene glycol shear thickening fluid

IF 1.7 4区 工程技术 Q4 POLYMER SCIENCE Journal of Polymer Engineering Pub Date : 2024-02-10 DOI:10.1515/polyeng-2023-0169
Gursimran Kaur, Karamjit Singh, Sanjeev Kumar Verma
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Abstract

The rheological characterization of STFs plays an essential role in understanding the suspension’s stability and the structural changes that occur under the impact of shear forces. This study aims to investigate the rheological behavior of STF after adding titanium diboride (TiB2) as an additive. STF modified with 2 % w/W TiB2 compared to other concentrations (1 %, 1.25 %, and 3 %) showed a maximum rise in viscosity (max), i.e., 18,484 Pa s during steady state rheology, as compared to untreated STF. In dynamic rheology, the same sample demonstrated maximum values of G′ and G″ at a constant frequency of 30 rad/s, G′ and G″ improved by 25 and 11 times, respectively, over unmodified STF. Furthermore, for constant strain amplitudes, the maximum values of G′ and G″ were observed at a strain amplitude of 700 %. G′ and G″ improved by approximately 6.5 and 6 times over unmodified STF, respectively. The findings of the dynamic and steady-state rheological analyses demonstrated that integrating TiB2 into the STF improved the ST behavior.
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二硼化钛对硅基聚乙二醇剪切增稠液流变特性的影响
STF 的流变特性对于了解悬浮液的稳定性以及在剪切力作用下发生的结构变化至关重要。本研究旨在探讨添加二硼化钛(TiB2)后 STF 的流变行为。与其他浓度(1%、1.25% 和 3%)的 STF 相比,添加 2% w/W TiB2 改性的 STF 与未处理的 STF 相比,在稳态流变过程中粘度(最大值)上升最大,达到 18,484 Pa s。在动态流变学中,同一样品在 30 弧度/秒的恒定频率下显示出 G′和 G″ 的最大值,G′和 G″ 分别比未经改性的 STF 提高了 25 倍和 11 倍。此外,对于恒定应变振幅,G′和 G″ 的最大值出现在应变振幅为 700 % 时。与未修正的 STF 相比,G′ 和 G″ 分别提高了约 6.5 倍和 6 倍。动态和稳态流变分析结果表明,在 STF 中加入 TiB2 改善了 ST 行为。
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来源期刊
Journal of Polymer Engineering
Journal of Polymer Engineering 工程技术-高分子科学
CiteScore
3.20
自引率
5.00%
发文量
95
审稿时长
2.5 months
期刊介绍: Journal of Polymer Engineering publishes reviews, original basic and applied research contributions as well as recent technological developments in polymer engineering. Polymer engineering is a strongly interdisciplinary field and papers published by the journal may span areas such as polymer physics, polymer processing and engineering of polymer-based materials and their applications. The editors and the publisher are committed to high quality standards and rapid handling of the peer review and publication processes.
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