{"title":"Bimetallic NiWO4 as an Efficient Interface Modulator for Pd Towards Enhanced Alcohol Electro-oxidation","authors":"","doi":"10.1007/s12678-024-00863-0","DOIUrl":null,"url":null,"abstract":"<h3>Abstract</h3> <p>The electronic coupling effect by interfacial engineering between noble metal and transition metal tungstates is considered an effective strategy for improving electrocatalytic activity. Herein we introduced a new hybrid electrocatalyst consisting of Pd nanoparticle supported on NiWO<sub>4</sub> nanocrystals modified carbon for efficient alcohol electro-oxidation reaction. Bimetallic oxide resulted as an efficient interface modulator for Pd over mono metallic oxides. The synthesised catalyst, Pd over nickel tungstate modified Vulcan, exhibited well-dispersed homogeneous Pd particles. The catalytic effectiveness for the electro-oxidation of methanol and ethanol was found to be enhanced around ten times (1202.48 mA/mg<sub>Pd</sub>) and six times (1508.24 mA/mg<sub>Pd</sub>), respectively compared to Pd deposited over C catalyst. The enhanced electrochemical property owing to electronic modification and improved surface area, by the strong coupling of Pd with nickel tungstate and carbon support conferred excellent catalytic performance for the synthesised catalyst. </p> <span> <h3>Graphical Abstract</h3> <p> <span> <span> <img alt=\"\" src=\"https://static-content.springer.com/image/MediaObjects/12678_2024_863_Figa_HTML.png\"/> </span> </span></p> </span>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrocatalysis","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s12678-024-00863-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The electronic coupling effect by interfacial engineering between noble metal and transition metal tungstates is considered an effective strategy for improving electrocatalytic activity. Herein we introduced a new hybrid electrocatalyst consisting of Pd nanoparticle supported on NiWO4 nanocrystals modified carbon for efficient alcohol electro-oxidation reaction. Bimetallic oxide resulted as an efficient interface modulator for Pd over mono metallic oxides. The synthesised catalyst, Pd over nickel tungstate modified Vulcan, exhibited well-dispersed homogeneous Pd particles. The catalytic effectiveness for the electro-oxidation of methanol and ethanol was found to be enhanced around ten times (1202.48 mA/mgPd) and six times (1508.24 mA/mgPd), respectively compared to Pd deposited over C catalyst. The enhanced electrochemical property owing to electronic modification and improved surface area, by the strong coupling of Pd with nickel tungstate and carbon support conferred excellent catalytic performance for the synthesised catalyst.
期刊介绍：
Electrocatalysis is cross-disciplinary in nature, and attracts the interest of chemists, physicists, biochemists, surface and materials scientists, and engineers. Electrocatalysis provides the unique international forum solely dedicated to the exchange of novel ideas in electrocatalysis for academic, government, and industrial researchers. Quick publication of new results, concepts, and inventions made involving Electrocatalysis stimulates scientific discoveries and breakthroughs, promotes the scientific and engineering concepts that are critical to the development of novel electrochemical technologies.
Electrocatalysis publishes original submissions in the form of letters, research papers, review articles, book reviews, and educational papers. Letters are preliminary reports that communicate new and important findings. Regular research papers are complete reports of new results, and their analysis and discussion. Review articles critically and constructively examine development in areas of electrocatalysis that are of broad interest and importance. Educational papers discuss important concepts whose understanding is vital to advances in theoretical and experimental aspects of electrochemical reactions.
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