Self-Immolative Polymers: From Synthesis to Applications

IF 10.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Annual Review of Materials Research Pub Date : 2024-02-16 DOI:10.1146/annurev-matsci-080222-104556
Jue Gong, Burak Tavsanli, Elizabeth R. Gillies
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Abstract

Polymers undergoing controlled degradation are of significant current interest. Among the classes of degradable polymers, self-immolative polymers (SIPs) are attracting increasing attention due to their ability to completely depolymerize from end to end following the cleavage of their endcap or backbone. Their amplified responses to stimuli, along with their ability to readily tune the stimulus to which they respond by changing only their endcap, are useful features for a variety of applications. This review covers the major classes of SIPs, including poly(benzyl carbamate)s, poly(benzyl ether)s, polyphthalaldehydes, polyglyoxylates, polydisulfides, polythioesters, and their related derivatives along with their endcaps. Distinctive features of their syntheses and depolymerizations are discussed. Applications of SIPs including imaging and sensing, therapeutics, gels, micro- and nanopatterning, transient or recyclable materials, and adhesives are described. We conclude with some challenges and future perspectives for the field.Expected final online publication date for the Annual Review of Materials Research, Volume 54 is July 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
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自侵蚀聚合物:从合成到应用
目前,可控降解聚合物备受关注。在各类可降解聚合物中,自惰性聚合物(SIP)因其能够在端盖或骨架裂解后从头到尾完全解聚而日益受到关注。它们对刺激的反应幅度大,而且只需改变端盖就能随时调整对刺激的反应,这些特点对各种应用都很有用。本综述涵盖了 SIPs 的主要类别,包括聚(氨基甲酸苄酯)、聚(苄基醚)、聚邻苯二甲酸酯、聚乙醛、聚二硫化物、聚硫醚及其相关衍生物,以及它们的封端。本文讨论了它们合成和解聚的显著特点。我们还介绍了 SIPs 的应用,包括成像和传感、治疗、凝胶、微观和纳米图案、瞬时或可回收材料以及粘合剂。最后,我们提出了该领域面临的一些挑战和未来展望。《材料研究年度综述》第 54 卷的最终在线出版日期预计为 2024 年 7 月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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来源期刊
Annual Review of Materials Research
Annual Review of Materials Research 工程技术-材料科学:综合
CiteScore
17.70
自引率
1.00%
发文量
21
期刊介绍: The Annual Review of Materials Research, published since 1971, is a journal that covers significant developments in the field of materials research. It includes original methodologies, materials phenomena, material systems, and special keynote topics. The current volume of the journal has been converted from gated to open access through Annual Reviews' Subscribe to Open program, with all articles published under a CC BY license. The journal defines its scope as encompassing significant developments in materials science, including methodologies for studying materials and materials phenomena. It is indexed and abstracted in various databases, such as Scopus, Science Citation Index Expanded, Civil Engineering Abstracts, INSPEC, and Academic Search, among others.
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