Research Progress on Stability Control on Ni-Based Catalysts for Methane Dry Reforming

Methane Pub Date : 2024-02-06 DOI:10.3390/methane3010006
Minghui Wei, Xuerong Shi
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Abstract

CO2 reforming of CH4 (DRM) utilizes the greenhouse gases of CH4 and CO2 to obtain the synthesis gas, benefiting the achievement of carbon neutrality. However, the deactivation of Ni-based catalysts caused by sintering and carbon deposition limits the industrial application. Focusing on stability improvement, this review first summarizes the reaction mechanism and deactivation mechanism in DRM and then discusses the impact of catalyst active components, supports, and interfacial structure. Finally, we propose the design direction of stable Ni-based catalysts towards DRM, providing guidance for the future development of catalysts suitable for industrial production.
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用于甲烷干法转化的镍基催化剂稳定性控制研究进展
二氧化碳重整甲烷(DRM)利用甲烷和二氧化碳这两种温室气体获得合成气,有利于实现碳中和。然而,烧结和碳沉积导致的镍基催化剂失活限制了其工业应用。本综述以提高稳定性为重点,首先总结了 DRM 的反应机理和失活机理,然后讨论了催化剂活性组分、支撑剂和界面结构的影响。最后,我们提出了面向 DRM 的稳定镍基催化剂的设计方向,为今后开发适合工业生产的催化剂提供指导。
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