Quality Improvement of Pea Protein Isolate‐Based Film: Effect of Sodium Carboxymethyl Cellulose on Film

Starch Pub Date : 2024-02-20 DOI:10.1002/star.202200253
Peiyun Jiang, Guiyun Chen, Shunying Xu, Jiaojiao Yu, Zihan Qu, Shuhong Li, Ye Chen
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Abstract

Sodium carboxymethyl cellulose (CMC) is cross‐linked with pea protein isolate (PPI) to prepare pea protein isolate/sodium carboxymethyl cellulose (PPI/CMC) composite film by the diffusion method. The effects of the mass fraction of CMC on the mechanical properties and water resistance of PPI/CMC composite film are investigated. In the film containing 0.4% CMC, the water vapor permeability (1.43 × 10−7 g m (m2∙h∙Pa)−1) is significantly decreased, while the water contact angle value is elevated (55.76°). The tensile strength of the composite film is enhanced by 54.45%, while the elongation at break is increased by 23.30%. The film has excellent thermal stability and a homogenous structure. The remarkable changes may be attributed to new chemical interactions (hydrogen bonds) between CMC and PPI as revealed by Fourier transform infrared spectroscopy. Further, the composite film has great advantages in water resistance after comparison. The film is applied to the fresh bean skin, effectively blocking and reducing the tearing force between the fresh bean skin, and consequently easy separation after soaking in water for 20 min. Overall, the inclusion of CMC effectively solves the functional limitation caused by the hydrophilicity of PPI film, paving the way for its effective application as a novel edible packaging film in conventional foods.

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豌豆蛋白异构体薄膜的质量改进:羧甲基纤维素钠对薄膜的影响
采用扩散法将羧甲基纤维素钠(CMC)与豌豆蛋白分离物(PPI)交联制备豌豆蛋白分离物/羧甲基纤维素钠(PPI/CMC)复合薄膜。研究了 CMC 质量分数对 PPI/CMC 复合薄膜机械性能和耐水性的影响。在含 0.4% CMC 的薄膜中,水蒸气渗透率(1.43 × 10-7 g m (m2∙h∙Pa)-1)显著降低,而水接触角值则升高(55.76°)。复合薄膜的拉伸强度提高了 54.45%,断裂伸长率提高了 23.30%。薄膜具有优异的热稳定性和均匀的结构。傅里叶变换红外光谱显示,这些明显的变化可能归因于 CMC 和 PPI 之间新的化学作用(氢键)。此外,经过比较,复合薄膜在耐水性方面也有很大优势。薄膜贴在新鲜豆皮上,能有效阻隔和降低新鲜豆皮之间的撕裂力,因此在水中浸泡 20 分钟后很容易分离。总之,CMC 的加入有效解决了 PPI 薄膜亲水性带来的功能限制,为其作为新型食用包装膜在传统食品中的有效应用铺平了道路。
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