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Effects of Different Dehulling Methods on Physical and Chemical Properties of Tartary Buckwheat Flour 不同脱壳方法对鞑靼荞麦粉理化性质的影响
Pub Date : 2024-09-17 DOI: 10.1002/star.202400082
Zhong Haixia, Yang Xijuan, She Yongxin, Shi Bibo, Xiao Shiming, Wang Anhu, Chen Zhiguang
Dehulling is a necessary step in the processing of Tartary buckwheat products. In this study, the effects of three different dehulling methods on the starch structure and physical and chemical properties of Tartary buckwheat are systematically analyzed. The results show that, first, explosion‐puffing dehulling treatment (EPT) destroys many of the starch granules, increases the average granular size by 261.7%, and decreases the ∆H by 66.5%; steam dehulling treatment (ST) and dry heat dehulling treatment (DHT) have no significant destructive effect on starch granules. Second, EPT increases the brightness and whiteness and decreases the Hausner ratio and Carr index of Tartary buckwheat flour, which gives Tartary buckwheat flour better fluidity and sensory quality. Third, EPT results in lower packed bulk density and smaller solubility changes with varying temperatures (50–90 °C), indicating that EPT is more applicable to the production of buckwheat tea. Fourth, ST achieves lower adhesiveness, higher hardness, and higher springiness, indicating that ST is more suitable for the production of buckwheat gel products. Fifth, DHT maximizes the retention of resistant starch (RS). ST maximizes rutin retention in buckwheat rice. These results can be used as a reference for selecting different dehulling methods for different buckwheat products.
脱壳是鞑靼荞麦产品加工的一个必要步骤。本研究系统分析了三种不同脱壳方法对鞑靼荞麦淀粉结构和理化性质的影响。结果表明:首先,爆炸膨化脱壳处理(EPT)破坏了许多淀粉颗粒,使平均粒度增加了 261.7%,∆H 降低了 66.5%;蒸汽脱壳处理(ST)和干热脱壳处理(DHT)对淀粉颗粒没有明显的破坏作用。其次,EPT 增加了鞑靼荞麦粉的白度和亮度,降低了豪斯纳比率和卡尔指数,使鞑靼荞麦粉具有更好的流动性和感官质量。第三,EPT 使包装体积密度降低,溶解度随温度变化(50-90 °C)而变化较小,表明 EPT 更适用于苦荞茶的生产。第四,ST 可实现较低的粘附性、较高的硬度和较高的回弹性,表明 ST 更适合生产苦荞凝胶产品。第五,DHT 能最大限度地保留抗性淀粉(RS)。ST 能最大限度地保留荞麦米中的芦丁。这些结果可作为不同荞麦产品选择不同脱壳方法的参考。
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引用次数: 0
Contents: Starch ‐ Stärke 9–10/2024 内容:淀粉 - 强度 9-10/2024
Pub Date : 2024-09-13 DOI: 10.1002/star.202470041
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引用次数: 0
Research Progress on Structure and Bioactivity of Polysaccharides from Platycodon grandiflorum 桔梗多糖的结构与生物活性研究进展
Pub Date : 2024-09-13 DOI: 10.1002/star.202400086
Jiaxin Chen, Xiaolong Ji, Xin Du, Rongling Xu, Fengcheng Shi, Xudan Guo
Platycodon grandiflorum is a commonly used Chinese herbal medicine in China, containing saponins, flavonoids, phenolic compounds, fatty acids, volatile oils, polysaccharides, and other active ingredients. It has the effects of regulating immunity, anti‐inflammatory, expectorant, lowering blood lipids, antioxidation, etc., and can be used to treat symptoms such as cough, sore throat, lung pain, and expectoration. Polysaccharides are one of the important bioactive substances in P. grandiflorum, which have better anti‐tumor and enhancing immune activity, and are widely used in medicine, health food, and other fields. P. grandiflorum polysaccharide (PGP) has various biological activities and is the main component and key bioactive substance of P. grandiflorum. It has various biological effects, including immune regulation, antioxidant, anti‐tumor, liver protection, hypoglycemic, and gastrointestinal protection. This paper systematically reviews the research progress on the extraction, separation and purification, structural characteristics, and biological activity of P. grandiflorum polysaccharides in recent years both domestically and internationally, to provide the theoretical basis for improving the utilization of P. grandiflorum polysaccharides and further studying the structure–activity relationship of P. grandiflorum polysaccharides.
桔梗是我国常用的中药材,含有皂苷、黄酮、酚类化合物、脂肪酸、挥发油、多糖等有效成分。具有调节免疫、消炎、祛痰、降血脂、抗氧化等功效,可用于治疗咳嗽、咽痛、肺痛、祛痰等症状。多糖是大花蒌中重要的生物活性物质之一,具有较好的抗肿瘤和增强免疫活性的作用,被广泛应用于医药、保健食品等领域。大花蒌多糖(PGP)具有多种生物活性,是大花蒌的主要成分和关键生物活性物质。它具有免疫调节、抗氧化、抗肿瘤、保肝、降血糖、保护胃肠道等多种生物作用。本文系统地综述了近年来国内外对葛根多糖的提取、分离纯化、结构特征、生物活性等方面的研究进展,为提高葛根多糖的利用率和进一步研究葛根多糖的结构-活性关系提供理论依据。
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引用次数: 0
Issue Information: Starch ‐ Stärke 9–10/2024 发行信息:淀粉 - 淀粉 9-10/2024
Pub Date : 2024-09-13 DOI: 10.1002/star.202470040
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引用次数: 0
Electrification of Oxidized Starch Production – Influence on Product Quality 氧化淀粉生产电气化 - 对产品质量的影响
Pub Date : 2024-09-12 DOI: 10.1002/star.202300201
Roel Bisselink, Michael Polhuis, Johan W. Timmermans, Jacco van Haveren, Ted M. Slaghek
Industrial starch oxidations are commonly carried out using sodium hypochlorite (NaOCl). Electrification of this process via continuous generation of NaOCl from sodium chloride (NaCl) in situ has the potential to substantially lower the environmental impact thereof, as brine waste streams are reduced, while occupational health and safety risks associated with the use of NaOCl, such as during transport, handling, and storage, can also be minimized. In the present study, the influence of continuous electrochemical generation of NaOCl from NaCl on the quality of the starch oxidation process is evaluated based on measurements of oxidized starch carboxylate contents (DSCO2H), molecular weights (Mws), and pasting characteristics in comparison to those of commercially available reference oxidized starches produced by oxidation with NaOCl in batch suspension processes. Recycling of the NaCl solution and how this affects the quality of the oxidized starch products is also investigated. By successfully preparing oxidized granular starches almost identical to the reference starches, the results show that it is feasible to electrify the oxidation process and that the original NaCl chloride solution can be recycled at least four times for in situ electrochemical generation of NaOCl.
工业淀粉氧化通常使用次氯酸钠(NaOCl)。通过就地从氯化钠(NaCl)中连续生成 NaOCl 来实现该工艺的电气化,有可能大大降低其对环境的影响,因为盐水废物流可以减少,同时与使用 NaOCl 相关的职业健康和安全风险(如运输、处理和储存过程中的风险)也可以降至最低。在本研究中,根据氧化淀粉羧酸盐含量 (DSCO2H)、分子量 (Mws) 和糊化特性的测量结果,评估了从 NaCl 中连续电化学生成 NaOCl 对淀粉氧化工艺质量的影响,并与批量悬浮工艺中使用 NaOCl 氧化生产的市售参考氧化淀粉进行了比较。此外,还研究了氯化钠溶液的循环以及这如何影响氧化淀粉产品的质量。通过成功制备与参考淀粉几乎完全相同的氧化颗粒淀粉,结果表明使氧化过程电气化是可行的,原始氯化钠溶液可循环使用至少四次,用于原位电化学生成 NaOCl。
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引用次数: 0
Effect of the Presence of Physiological Disorder Recognized as “yellow berry” on the Quality of Starch in Bread Wheat (Triticum aestivum) and Durum Wheat (Triticum durum) 被称为 "黄浆果 "的生理紊乱对面包小麦(Triticum aestivum)和硬质小麦(Triticum durum)淀粉质量的影响
Pub Date : 2024-09-12 DOI: 10.1002/star.202400059
Cindy Veronica Padilla‐Torres, Guadalupe Amanda López‐Ahumad, Iram Mondaca‐Fernández, José de Jesús de Balderas‐Cortés, María Mercedes Meza‐Montenegro, Sergio Othon Serna‐Saldívar, Lorena Carolina Sosa‐Yáñez, Ramón Francisco Dórame‐Miranda, Marcela Gaytán‐Martínez
Genetic and environmental factors influence wheat grain quality, including vitreousness, protein, and starch content. Yellow berry (YB), a physiological condition, adversely affects wheat quality, particularly in irrigated fields with limited nitrogen application, leading to starch‐rich, low‐protein grains. This study examines common wheat, used in baking industries, and durum wheat, primarily employs for pasta production. The focus is on investigating how the physicochemical properties of these wheat types change with the presence of YB, that impacts protein content negatively, increasing total starch content. Fourier‐transform infrared spectroscopy reveals structural changes in YB‐affected grains, while X‐ray diffraction indicates varying crystallinity. In determination of amylose, an increase of 6% in bread wheat with YB and 3% in durum wheat with YB is observed. In the case of RVA (Rapid Visco Analyzer) analysis, a notable increase in viscosity is evident in the treatments that included the yellow berry. This finding suggests that YB is associated with substantial modifications in starch properties, such as amylose‐to‐amylopectin ratio, chain length, and degree of branching, among several other components, which may have important implications for the texture and quality of food products. This study calls for further research to mitigate YB's impact and enhances the quality of wheat‐derived foods.
遗传和环境因素会影响小麦籽粒的品质,包括颖果率、蛋白质和淀粉含量。黄浆果(YB)是一种生理状况,会对小麦品质产生不利影响,尤其是在施氮量有限的灌溉田中,会导致小麦籽粒富含淀粉、蛋白质含量低。本研究考察了用于烘焙业的普通小麦和主要用于面食生产的硬质小麦。YB对蛋白质含量有负面影响,但会增加总淀粉含量。傅立叶变换红外光谱显示了受 YB 影响的麦粒的结构变化,而 X 射线衍射则显示了不同的结晶度。在测定直链淀粉时发现,受 YB 影响的面包小麦中的直链淀粉含量增加了 6%,受 YB 影响的硬质小麦中的直链淀粉含量增加了 3%。在 RVA(快速粘度分析仪)分析中,含有黄色浆果的处理明显增加了粘度。这一发现表明,YB 与淀粉特性的实质性改变有关,例如直链淀粉与支链淀粉的比例、链长、分支程度以及其他一些成分,这可能会对食品的质地和质量产生重要影响。这项研究呼吁进一步开展研究,以减轻 YB 的影响并提高小麦食品的质量。
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引用次数: 0
Effect of Organic Acids as Additives on Buckwheat Starch Films Produced by Casting 有机酸添加剂对荞麦淀粉浇铸薄膜的影响
Pub Date : 2024-09-12 DOI: 10.1002/star.202400030
Fernanda Gabriela Henning, Ivo Mottin Demiate, Renata Dinnies Santos Salem, Vanessa Soltes de Almeida, Luiz Gustavo Lacerda
The aim of this research is to investigate the influence of food‐grade organic acids incorporation in buckwheat starch films obtained by casting. Buckwheat starch is extracted via the alkaline methodology, and the impact of different acids and concentrations on film properties is evaluated. The films are submitted to the following characterizations: mechanical and moisture resistance properties, water vapor permeability (WVP), thermogravimetry (TG), field emission gun scanning electron microscopy (FEG‐SEM), and ATR‐FTIR (Attenuated Total Reflectance‐Fourier Transform Infrared) spectroscopy. Incorporating organic acids show film moisture reduction, WVP, and increased thermal stability. Among the organic acids tested, the films with tartaric and citric acids provide the most positive impact on the films’ mechanical and water resistance. In contrast, malic acid is demonstrated to have a less efficient crosslinking capacity.
本研究旨在探讨食品级有机酸对荞麦淀粉浇铸薄膜的影响。通过碱性方法提取荞麦淀粉,并评估不同酸和浓度对薄膜特性的影响。对薄膜进行了以下表征:机械和防潮性能、水蒸气渗透性(WVP)、热重(TG)、场发射枪扫描电子显微镜(FEG-SEM)和衰减全反射-傅立叶变换红外光谱(ATR-FTIR)。加入有机酸后,薄膜的湿度降低,WVP 增加,热稳定性提高。在测试的有机酸中,含有酒石酸和柠檬酸的薄膜对薄膜的机械性能和耐水性有最积极的影响。相比之下,苹果酸的交联能力较弱。
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引用次数: 0
Physiochemical, Pasting, and Morphological Properties of Native Oat Starch and Citrate‐Modified Oat Starch 原生燕麦淀粉和柠檬酸盐改性燕麦淀粉的理化、糊化和形态特性
Pub Date : 2024-09-09 DOI: 10.1002/star.202400063
Vanessa Alexander, Trust Beta, Lovemore Nkhata Malunga
Starch is widely utilized in the food industry, but its native form may have limitations in terms of functionality and nutrition. This study examines the characteristics of native oat starch and explores its potential for chemical modification by cross‐linking, with the aim of gaining a deeper understanding of its functionality. Citrate‐modified oat starch (COS) is generated by cross‐linking native oat starch (NOS) with citric acid. Chemical analysis reveals distinctions between NOS and COS, notably in terms of resistant starch content, which is elevated in COS. X‐ray diffraction (XRD) results reveal that NOS exhibits crystalline peaks characteristic of A‐type starch, distinguishing it from COS. In contrast, COS displays absent crystalline peaks, attributed to cross‐linking. Swelling factor, solubility, and paste clarity along with most of the pasting properties are found to be significantly lower for COS compared to NOS. The scanning electron microscopic images show how cross‐linking can alter the morphology of the NOS. The findings from this investigation highlight significant distinctions between NOS and COS. The cross‐linking process successfully enhances the resistant starch content and imparted distinctive properties absent in native oat starch. Consequently, there is potential for incorporating modified oat starch as a food ingredient.
淀粉在食品工业中被广泛使用,但其原生形态在功能和营养方面可能存在局限性。本研究考察了原生燕麦淀粉的特性,并探讨了通过交联对其进行化学改性的潜力,目的是加深对其功能的了解。柠檬酸盐改性燕麦淀粉(COS)是由原生燕麦淀粉(NOS)与柠檬酸交联生成的。化学分析揭示了 NOS 和 COS 之间的区别,特别是抗性淀粉含量,COS 中的抗性淀粉含量更高。X 射线衍射(XRD)结果显示,NOS 显示出 A 型淀粉特有的结晶峰,从而与 COS 区分开来。与此相反,COS 则不显示结晶峰,这归因于交联。与 NOS 相比,COS 的膨胀因子、溶解度、糊状物透明度以及大多数粘贴特性都明显较低。扫描电子显微镜图像显示了交联如何改变 NOS 的形态。这项研究结果突出了 NOS 和 COS 之间的显著区别。交联工艺成功地提高了抗性淀粉的含量,并赋予了原生燕麦淀粉所不具备的独特特性。因此,将变性燕麦淀粉作为食品配料是有潜力的。
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引用次数: 0
Effect of the Ratio of Soluble and Insoluble Dietary Fiber from Rice Bran with Extrusion Cooking Treatment on Pasting, Thermal, and Structural Properties of Rice Starch Gel 米糠中可溶性和不可溶性膳食纤维的比例与挤压蒸煮处理对大米淀粉凝胶的糊化、热和结构特性的影响
Pub Date : 2024-09-09 DOI: 10.1002/star.202400008
Lei‐Xin Wang, Yu‐Hui Ma, Ying‐Guo Lv, Na‐Na Wu, Bin Tan
This study aims to investigate the effect of different ratios of soluble and insoluble dietary fiber (0/100, 25/75, 40/60, 55/45, 70/30, 85/15, 100/0) in rice bran treated with or without extrusion cooking on the physicochemical and structural properties of rice starch. As the ratio of soluble dietary fiber (SDF) increases, the PV (peak viscosity), FV (final viscosity), SB (setback value), and BD (breakdown value) of starch are significantly decreased, indicating that a higher SDF ratio can delay the short‐term retrogradation of starch. Compared with the unextruded rice bran SDF/IDF starch gel, the content of weak bond water and free water in the extruded rice bran SDF/IDF starch gel is higher while the content of strong bond water in the starch gel is lower at the same SDF/IDF ratio. Meanwhile, for the results X‐ray diffraction (XRD) and fourier transform infrared spectrum (FTIR), the rice starch with the extruded rice bran SDF/IDF ratio of 25:75 shows the lowest relative crystallinity of 3.48% and the lowest peak to height ratio of FTIR (1047 cm−1/1022 cm−1) of 1.0746, suggesting that the inhibition effect on rice starch retrogradation is better. This may be beneficial for the utilization of different ratios of SDF/IDF from extruded rice bran and physicochemical properties improvement of rice starch gel.
本研究旨在探讨米糠中可溶性和不可溶性膳食纤维的不同比例(0/100、25/75、40/60、55/45、70/30、85/15、100/0)经挤压蒸煮处理或不经挤压蒸煮处理对大米淀粉的物理化学和结构特性的影响。随着可溶性膳食纤维(SDF)比例的增加,淀粉的峰值粘度(PV)、最终粘度(FV)、后退值(SB)和分解值(BD)均显著降低,表明较高的 SDF 比例可延缓淀粉的短期逆变。与未挤压的米糠 SDF/IDF 淀粉凝胶相比,在相同的 SDF/IDF 比例下,挤压米糠 SDF/IDF 淀粉凝胶中弱结合水和自由水的含量较高,而淀粉凝胶中强结合水的含量较低。同时,从 X 射线衍射(XRD)和傅立叶变换红外光谱(FTIR)结果来看,挤压米糠 SDF/IDF 比例为 25:75 的米淀粉相对结晶度最低,为 3.48%,傅立叶变换红外光谱峰高比(1047 cm-1/1022 cm-1)最低,为 1.0746,表明其对米淀粉逆变的抑制效果较好。这可能有利于利用挤压米糠中不同比例的 SDF/IDF 和改善米淀粉凝胶的理化性质。
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引用次数: 0
Physicochemical, Structural, and Functional Properties of Cacahuacintle Maize Starch Cacahuacintle 玉米淀粉的物理化学、结构和功能特性
Pub Date : 2024-09-05 DOI: 10.1002/star.202400113
Diana Edith López‐Vázquez, Consuelo Lobato‐Calleros, Landy Hernández‐Rodríguez, Eleazar Aguirre‐Mandujano, José Alvarez‐Ramirez, Eduardo Jaime Vernon‐Carter
Maize is a valuable source of starch, but many genotypes still have not yet been studied. Thus, an ongoing research topic is to evaluate the physicochemical, structural, and functional properties of these understudied genotypes, such as is the case of the cacahuacintle maize genotype. Two cacahuacintle maize varieties MA1 and MA2, endogenous to the State of Mexico but from different locations, are used for obtaining maize starch (MS1 and MS2) and compared to a commercial normal maize starch (CS). Scanning electron microscopy (SEM) reveals that CS granules have polyhedral shape, while those for MS1 and MS2 are semi‐spherical. Fourier‐transform infrared (FTIR) spectra shows that the three starches exhibit the characteristic peaks of polysaccharides but display differences in the hydrated and ordered structures. X‐ray analysis reveals that all the starches have Type A pattern, but have different crystallinities, ranging from 21.07% to 25.37%. MS1 and MS2 exhibit higher values of solubility, swelling power, and water retention capacity compared to CS, but the latter has superior oil‐holding capacity. MS1 and MS2 have higher resistant starch fraction content than CS. The results show that cacahuacintle maize starch has a good application potential as an additive in food products.
玉米是一种宝贵的淀粉来源,但许多基因型尚未得到研究。因此,一个正在进行的研究课题是评估这些未被充分研究的基因型的物理化学、结构和功能特性,例如 cacahuacintle 玉米基因型。墨西哥州内生但产地不同的两个 cacahuacintle 玉米品种 MA1 和 MA2 被用来获取玉米淀粉(MS1 和 MS2),并与商用普通玉米淀粉(CS)进行比较。扫描电子显微镜(SEM)显示,CS 的颗粒呈多面体状,而 MS1 和 MS2 的颗粒呈半球状。傅立叶变换红外光谱(FTIR)显示,三种淀粉都呈现出多糖的特征峰值,但在水合结构和有序结构方面存在差异。X 射线分析表明,所有淀粉都具有 A 型模式,但结晶度不同,从 21.07% 到 25.37%。与 CS 相比,MS1 和 MS2 具有更高的溶解度、膨胀力和保水能力,但后者的保油能力更强。MS1 和 MS2 的抗性淀粉含量高于 CS。结果表明,玉米淀粉作为食品添加剂具有良好的应用潜力。
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引用次数: 0
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