Synthesis of nitrogen-doped graphene coupled acid fuchsin photocatalyst turns aryl-vinyl into aromatic aldehydes under visible light

Manish, Rajesh K. Yadav, Satyam Singh, Rehana Shahin, Chandani Singh, Ripsa Rani Nayak, A. P. Singh, D. Tiwary, Pramod Kumar, Jin‐Ook Baeg, N. K. Gupta
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Abstract

A schematic strategy is presented to overcome the problem of low photocatalytic performance of graphene. Herein, we synthesized nitrogen-doped graphene (NDG)-coupled acid fuchsin (AF) photocatalyst, i.e.; NDGCAF photocatalyst. The NDGCAF photocatalyst has excellent solar light harvesting ability, band gap suitability, and high molar extinction coefficient than the NDG photocatalyst. Due to these properties, the NDGCAF photocatalyst has the ability to oxidize aryl-vinyl into aryl-vinyl-aldehyde under the irradiation of visible light. In this context, it exhibited the utmost conversion efficiency of aryl-vinyl to aryl-vinyl-aldehyde with a good yield of 98.15% . Current research highlights the significant application of NDGCAF light-harvesting photocatalysts in the research field of organic transformations.
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氮掺杂石墨烯耦合酸性紫胶光催化剂的合成在可见光下将芳基乙烯基转化为芳香醛
为克服石墨烯光催化性能低的问题,我们提出了一种示意性策略。在此,我们合成了氮掺杂石墨烯(NDG)耦合酸性品红(AF)光催化剂,即 NDGCAF 光催化剂。与 NDG 光催化剂相比,NDGCAF 光催化剂具有出色的太阳光收集能力、带隙适宜性和较高的摩尔消光系数。基于这些特性,NDGCAF 光催化剂能够在可见光的照射下将芳基乙烯基氧化成芳基乙烯基醛。在这种情况下,它将芳基乙烯基转化为芳基乙烯基醛的转化率高达 98.15%。目前的研究凸显了 NDGCAF 光收集光催化剂在有机转化研究领域的重要应用。
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