Applicability of the Suspension Effect in Estimation of Influence Exerted by Ionic Composition of Flotation Pulp on Apatite Surface

IF 0.7 4区 工程技术 Q4 MINING & MINERAL PROCESSING Journal of Mining Science Pub Date : 2024-02-26 DOI:10.1134/s1062739123050149
A. V. Artem’ev, G. V. Mitrofanova
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Abstract

By means of determining the suspension effect, the authors studied the change in the surface properties of apatite under the action of reagents and ions present in flotation pulp during processing of apatite-bearing ore. It is shown that the ratio of acid–base centers of apatite surface change in interaction with ions HCO\(_3^-\), CO\(_3^{2-}\), HPO\(_2^{2-}\), cations Ca\(^{2 + }\) and oleate ions in distilled water and in water after deionization to remove carbon dioxide. The change in apatite surface properties in alkaline water shows up as quantitative superiority of base centers. Such ionization of mineral surface favors adsorption of cations, for example, Ca\(^{2 + }\), and sets background for more efficient interaction between anion-type agents. The data obtained from the studies of the suspension effect, correlate with the results of infrared spectroscopy of apatite treated by the appropriate agents.

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悬浮效应在估计浮选矿浆离子成分对磷灰石表面影响时的适用性
摘要 作者通过确定悬浮效应的方法,研究了在含磷灰石矿石加工过程中,浮选矿浆中存在的试剂和离子作用下磷灰石表面性质的变化。结果表明,在蒸馏水和去离子除去二氧化碳后的水中,磷灰石表面的酸碱中心比在与离子 HCO\(_3^-\), CO\(_3^{2-}\), HPO\(_2^{2-}\), 阳离子 Ca\(^{2 +\ }) 和油酸根离子的相互作用中发生了变化。碱水中磷灰石表面性质的变化表现为碱中心在数量上的优势。矿物表面的这种离子化有利于阳离子的吸附,例如 Ca\(^{2 + }\) ,并为阴离子型介质之间更有效的相互作用提供了背景。从悬浮效应研究中获得的数据与用适当药剂处理磷灰石的红外光谱结果相关。
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来源期刊
Journal of Mining Science
Journal of Mining Science 工程技术-矿业与矿物加工
CiteScore
1.70
自引率
25.00%
发文量
19
审稿时长
24 months
期刊介绍: The Journal reflects the current trends of development in fundamental and applied mining sciences. It publishes original articles on geomechanics and geoinformation science, investigation of relationships between global geodynamic processes and man-induced disasters, physical and mathematical modeling of rheological and wave processes in multiphase structural geological media, rock failure, analysis and synthesis of mechanisms, automatic machines, and robots, science of mining machines, creation of resource-saving and ecologically safe technologies of mineral mining, mine aerology and mine thermal physics, coal seam degassing, mechanisms for origination of spontaneous fires and methods for their extinction, mineral dressing, and bowel exploitation.
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Topicality of the Framework and General Theory for Safe Deep-Level Mining of Hydrocarbon-Bearing Formations Study on Loading Rate and Rock–Coal Strength Ratio Effect on Mechanical Properties of Coal–Rock Combination Interrelation of Mechanical Properties and Root Damage of Salix with Ground Surface Subsidence Experimental Investigation of Block Fracture Influence on P-Wave Propagation in Block Rock Mass Evolution Mechanism and Monitoring Technology of Overburden Deformation in Underground Mining with Grout Injection
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