High-Temperature Thermophysical Properties of Alloys of the Nickel–Vanadium System in Solid State

IF 1 4区 物理与天体物理 Q4 PHYSICS, APPLIED High Temperature Pub Date : 2024-02-29 DOI:10.1134/s0018151x23010029
E. R. Akhtyamov, V. I. Gorbatov, A. D. Ivliev, V. F. Polev, A. A. Kurichenko
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Abstract

We report on the thermal diffusivities, specific heats, thermal conductivities, and electrical resistivities of 21 alloys of the nickel–vanadium system. It is found that heat transfer in NiV alloys is mainly executed by electrons. The behavior of temperature dependences of these properties shows that in the temperature range under investigation, the thermophysical characteristics of samples in the state of solid solutions and intermetallic compounds differ significantly because of the dependence of the energy structure of collectivized electrons on the system composition and temperature. It is shown that the concentration range in which the mutual solubility of component is ensured expands upon heating. The Nordheim rule for the alloys under investigation holds at temperatures close to the melting point and indicates the dependence of the density of states of collectivized electrons on the concentration of components.

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固态镍钒系合金的高温热物理性质
摘要 我们报告了 21 种镍钒合金的热扩散率、比热、热导率和电阻率。研究发现,镍钒合金中的热传递主要由电子完成。这些特性的温度相关性表明,在所研究的温度范围内,固溶体和金属间化合物状态的样品的热物理特性差别很大,这是因为集合电子的能量结构取决于体系成分和温度。研究表明,在加热过程中,确保成分互溶的浓度范围会扩大。所研究合金的诺德海姆法则在接近熔点的温度下成立,并表明集合电子的状态密度取决于成分的浓度。
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来源期刊
High Temperature
High Temperature 物理-物理:应用
CiteScore
1.50
自引率
40.00%
发文量
0
审稿时长
4-8 weeks
期刊介绍: High Temperature is an international peer reviewed journal that publishes original papers and reviews written by theoretical and experimental researchers. The journal deals with properties and processes in low-temperature plasma; thermophysical properties of substances including pure materials, mixtures and alloys; the properties in the vicinity of the critical point, equations of state; phase equilibrium; heat and mass transfer phenomena, in particular, by forced and free convections; processes of boiling and condensation, radiation, and complex heat transfer; experimental methods and apparatuses; high-temperature facilities for power engineering applications, etc. The journal reflects the current trends in thermophysical research. It presents the results of present-day experimental and theoretical studies in the processes of complex heat transfer, thermal, gas dynamic processes, and processes of heat and mass transfer, as well as the latest advances in the theoretical description of the properties of high-temperature media.
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